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IfE^(@)(M^(+)/M)= -0.44V and E^(@)(X/X^(...

If`E^(@)(M^(+)/M)= -0.44V` and `E^(@)(X/X^(-)) = 0.33V`.
From this data one can conclude that:

A

`M+Xrightarrow M^(+)+X^(-)` is the spontaneous reaction

B

`M^(+)+ X^(-) rightarrow M+X` is the spontaneous reaction

C

`E_(cell)^(@) = 0.77V` for the feasible cell reaction

D

`E_(cell)^(@) = -0.77V`

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The correct Answer is:
To solve the problem, we need to analyze the given standard electrode potentials and draw conclusions about the spontaneity of the reactions involving the species M and X. ### Step-by-Step Solution: 1. **Identify the Given Standard Electrode Potentials**: - For the half-reaction \( M^{+}/M \): \( E^\circ = -0.44 \, \text{V} \) - For the half-reaction \( X/X^{-} \): \( E^\circ = 0.33 \, \text{V} \) 2. **Compare the Standard Electrode Potentials**: - The standard reduction potential for \( X/X^{-} \) (0.33 V) is greater than that for \( M^{+}/M \) (-0.44 V). This indicates that \( X \) has a greater tendency to be reduced than \( M^{+} \). 3. **Determine the Oxidation and Reduction Reactions**: - Since \( X \) is more likely to be reduced, it will act as the cathode in the electrochemical cell, while \( M \) will be oxidized. - The oxidation reaction can be written as: \[ M \rightarrow M^{+} + e^{-} \] - The reduction reaction can be written as: \[ X + e^{-} \rightarrow X^{-} \] 4. **Calculate the Standard Cell Potential \( E^\circ_{\text{cell}} \)**: - The standard cell potential is calculated using the formula: \[ E^\circ_{\text{cell}} = E^\circ_{\text{cathode}} - E^\circ_{\text{anode}} \] - Here, \( E^\circ_{\text{cathode}} = 0.33 \, \text{V} \) and \( E^\circ_{\text{anode}} = -0.44 \, \text{V} \). - Substituting the values: \[ E^\circ_{\text{cell}} = 0.33 \, \text{V} - (-0.44 \, \text{V}) = 0.33 \, \text{V} + 0.44 \, \text{V} = 0.77 \, \text{V} \] 5. **Determine the Spontaneity of the Reaction**: - A positive \( E^\circ_{\text{cell}} \) indicates that the reaction is spontaneous. Since \( E^\circ_{\text{cell}} = 0.77 \, \text{V} \), the reaction is spontaneous. 6. **Conclusion**: - The overall reaction is spontaneous, and we can conclude that: - \( M \) oxidizes to \( M^{+} \) and \( X \) reduces to \( X^{-} \). - The standard cell potential is \( 0.77 \, \text{V} \).

To solve the problem, we need to analyze the given standard electrode potentials and draw conclusions about the spontaneity of the reactions involving the species M and X. ### Step-by-Step Solution: 1. **Identify the Given Standard Electrode Potentials**: - For the half-reaction \( M^{+}/M \): \( E^\circ = -0.44 \, \text{V} \) - For the half-reaction \( X/X^{-} \): \( E^\circ = 0.33 \, \text{V} \) ...
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For the electrochemical cell, (M)|M^(+))||(X^(-)|X) . E^(@)(M^(+)//M)=0.44V and E^(@)(X//X^(-))=0.33V . From this data one can deduce that

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E^(@) of Fe^(2 +) //Fe = - 0.44 V, E^(@) of Cu //Cu^(2+) = -0.34 V . Then in the cell

Given that E_(M^(+)//M)^(@)=-0.44V and E_(X^(+)//X)^(@)=-0.33V at 298K . The value of E_("cell") for M(s)|M^(+)(0.1M)||X^(+)(0.2M)|X(s) at 298K will be [log 2=0.3,log3=0.48,log5=0.7]

E_(M^(3+)//(M))^(@) = -0.036V , E_(M^(2+)//M)^(@)= -0.439V . The value of standard electrode potential for the change, M^(3+)(aq) + e^(-)rightarrow M^(2+) (aq) will be :

The standard reduction potential data at 25^(@)C is given below E^(@) (Fe^(3+), Fe^(2+)) = +0.77V , E^(@) (Fe^(2+), Fe) = -0.44V , E^(@) (Cu^(2+),Cu) = +0.34V , E^(@)(Cu^(+),Cu) = +0.52 V , E^(@) (O_(2)(g) +4H^(+) +4e^(-) rarr 2H_(2)O] = +1.23V E^(@) [(O_(2)(g) +2H_(2)O +4e^(-) rarr 4OH^(-))] = +0.40V , E^(@) (Cr^(3+), Cr) =- 0.74V , E^(@) (Cr^(2+),Cr) = - 0.91V , Match E^(@) of the redox pair in List-I with the values given in List-II and select the correct answer using the code given below teh lists: {:(List-I,List-II),((P)E^(@)(Fe^(3+),Fe),(1)-0.18V),((Q)E^(@)(4H_(2)O hArr 4H^(+)+4OH^(+)),(2)-0.4V),((R)E^(@)(Cu^(2+)+Curarr2Cu^(+)),(3)-0.04V),((S)E^(@)(Cr^(3+),Cr^(2+)),(4)-0.83V):} Codes:

The standard reduction potential data at 25^(@)C is given below E^(@) (Fe^(3+), Fe^(2+)) = +0.77V , E^(@) (Fe^(2+), Fe) = -0.44V , E^(@) (Cu^(2+),Cu) = +0.34V , E^(@)(Cu^(+),Cu) = +0.52 V , E^(@) (O_(2)(g) +4H^(+) +4e^(-) rarr 2H_(2)O] = +1.23V E^(@) [(O_(2)(g) +2H_(2)O +4e^(-) rarr 4OH^(-))] = +0.40V , E^(@) (Cr^(3+), Cr) =- 0.74V , E^(@) (Cr^(2+),Cr) = - 0.91V , Match E^(@) of the redox pair in List-I with the values given in List-II and select the correct answer using the code given below the lists: {:(List-I,List-II),((P)E^(@)(Fe^(3+),Fe),(1)-0.18V),((Q)E^(@)(4H_(2)O hArr 4H^(+)+4OH^(-)),(2)-0.4V),((R)E^(@)(Cu^(2+)+Curarr2Cu^(+)),(3)-0.04V),((S)E^(@)(Cr^(3+),Cr^(2+)),(4)-0.83V):} Codes:

Copper from copper sulphate solution can be displacesd by. (The standard reduction potentials of some electrodes are given below): E^(o)(Fe^(2+)//Fe) = - 0.44 V, E^(o) (Zn^(2+)//Zn) = - 0.76 V E^(o) (Cu^(2+)//Cu) = + 0.34 V: E^(o)(Cr^(3+)//Cr) = - 0.74 V E^(o) (H^(+)// 1/2H_(2)) = 0.00V

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