Home
Class 12
CHEMISTRY
The standard electrode potential E^(@) ...

The standard electrode potential `E^(@)` and its temperature coefficient `((dE^(@))/(dT))` for a cell are 2V and `-5xx10^(-4) Vk^(-1)` at 300K respectively . The cell reaction is ` Zn(s)+ Cu^(2) (aq)+ Cu(S)` .
The standard reaction enthalpy `Delta_(r) H^(@)` at 300 K `KJmol^(-1)` is :
`([use R = 8 JK^(-1)mol^(-1)` and `F = 96000Cmol^(-1)])`

A

`206.4`

B

`-412.8`

C

`-384.0`

D

`192.0`

Text Solution

AI Generated Solution

To solve the problem, we need to determine the standard reaction enthalpy \(\Delta_r H^\circ\) at 300 K for the given cell reaction: \[ \text{Zn}(s) + \text{Cu}^{2+}(aq) \rightarrow \text{Zn}^{2+}(aq) + \text{Cu}(s) \] ### Step-by-Step Solution: 1. **Identify the Given Values:** - Standard electrode potential, \(E^\circ = 2 \, \text{V}\) ...
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|76 Videos
  • ELECTROCHEMISTRY

    VMC MODULES ENGLISH|Exercise FUNDAMENTAL|50 Videos
  • ELECTROCHEMISTRY

    VMC MODULES ENGLISH|Exercise Level-2|65 Videos
  • CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES

    VMC MODULES ENGLISH|Exercise JEE ADVANCE (ARCHIVE)|30 Videos
  • ENVIRONMENTAL CHEMISTRY

    VMC MODULES ENGLISH|Exercise JEE Main (Archive)|39 Videos

Similar Questions

Explore conceptually related problems

The standard electrode potential E^(Theta) and its temperature coefficent ((dE^Theta)/(d T)) for a cell are 2V and -5xx10^(-4)VK^(-1) at 300 K respectively. The cell reaction is Zn(s)+Cu^(2+)(aq)to Zn^(2+)(aq) +Cu(s) . The standard reaction enthalpy (Delta_(t)H^(Theta)) at 300 K is 4.12 xx10^(x) J//"mol" . Numerical value of x is _________________ [Use R=8JK^(-1)mol^(-1) and F=96,000 C "mol"^(-1) ].

The temperature coefficient of a given cell , ((delE)/(delT))_P is 1.5xx10^(-4) VK^(-1) at 300 K. The change in entropy of cell during the cource of reaction, Pb((s))+ HgCl_(2)((aq))rightarrowPbCl_(2) (aq)+ Hg(1)

If the standard electrode potential for a cell is 2V at 300 K, the equilibrium constant (K) for the reaction Zn(s) + Cu^(2+) (aq) at 300 k is approximately : (R=8JK^(-1) mol^(-1) , F= 96000 mol^(-1))

For a reversible reaction A hArr B . Find (log_(10)K)/(10) at 2727^(@) C temperature Given Delta_(r)H^(0) = - 54.07 kJ mol^(-1) Delta_(r)S^(0) = 10 JK^(-1) R = 8.314 JK^(-1) mol^(-1)

The equilibrium constant for a reaction is 10. What will be the value of DeltaG^@ ? R = 8.314 J K^(-1) mol^(-1), T = 300K.

If the standed electrode potential for a cell is 2 V at 300 K, the equilibrium constant (K) for the reaction Zn(s)+Cu^(2+)(aq) hArrZn^(2+)(aq)+Cu(s) at 300 K is approximately (R=8JK^(-1)mol^(-1),F=96000Cmol^(-1))

The voltage of the cell consisting of Li_((s)) and F_(2(g)) electrodes is 5.92 V at standard condition at 298 K. What is the voltage if the electrolyte consists of 2 M LiF. ("ln 2 = =0.693, R = 8.314 J K"^(-1)" mol"^(-1) and F = 96500" C mol"^(-1))

Given that K_(sp) of CuS=10^(-35) and E_Cu//Cu^(2+)= (-0.34V) . The standard oxidation potential of Cu|CuS|S^(2-) Half- cell is :

The standard Gibbs energy for the given cell reaction is KJmol^(-1) at 298 K is : Zn(s)+CU^(2+) (aq) rightarrow Zn^(2+) (aq) + Cu(s) E^(@)= 2V at 298 K (Friday's constant , F = 96000 C mol^-1 )

Calculate the standard free energy change for the following reaction Zn(s) + Cu^(2+)(aq) to Zn^(2+) (aq) + Cu(s) Given : Delta_fG^@ [Cu^(2+)(aq)] = 65.0kJ mol^(-1) Delta_f G^@ [ Zn^(2+) (aq)] = -147.2 kJ mol^(-1)

VMC MODULES ENGLISH-ELECTROCHEMISTRY-JEE Main (Archive)
  1. In the cell Pt(s)|H(2)(g,1bar)|HCl (aq)| AgCl(s)|Ag(S)|Pt(s) the cell ...

    Text Solution

    |

  2. For the cell Zn((s)) |ZN^(2+) ((aq)) || M^(X+)((aq))|M((s)), different...

    Text Solution

    |

  3. The standard electrode potential E^(@) and its temperature coefficien...

    Text Solution

    |

  4. ^^(m)^(@) for NaCI,HCI and NaA are 126.4,425.9 and 100.5Scm^2 m ol^(-1...

    Text Solution

    |

  5. Given the equilibrium constant : K(c) of the reaction : Cu(s) + 2Ag^...

    Text Solution

    |

  6. Consider the following reduction processes : Zn^(2+)+2e^(-)toZn(s), ...

    Text Solution

    |

  7. Consider the statements S1 and S2: S1: Conductivity always increases...

    Text Solution

    |

  8. The standard Gibbs energy for the given cell reaction is KJmol^(-1) at...

    Text Solution

    |

  9. Given that E(o(2)//H(2)O)^(Theta)= +1.23V, E(S(2)O(8)^(2-)//SO(4)^(2-...

    Text Solution

    |

  10. Given : Co^(3+) + e^(-) to Co^(2+) , E^(@) = +1.81V pb^(4+) + 2e^(-...

    Text Solution

    |

  11. The decreasing order of electrical conductivity of the following aqueo...

    Text Solution

    |

  12. The INCORRECT match in the following is :

    Text Solution

    |

  13. A solution of Ni(NO(3))(2) is electrolysed between platinum electrode...

    Text Solution

    |

  14. Calculate the standard cell potential (in V) of the cell in which foll...

    Text Solution

    |

  15. Which one of the following graphs between molar conductivity (A(m)) ...

    Text Solution

    |

  16. The equation that is incorrect is:

    Text Solution

    |

  17. For an electrochemical cell Sn(s)Sn^(2+) (aq,1M)||pb^(2+) (Aq,1M)|Pb(s...

    Text Solution

    |

  18. 108 g of silver (molar mass 108 g mol–1) is deposited at cathode from ...

    Text Solution

    |

  19. What would be the electrode potential for the given half cell reaction...

    Text Solution

    |

  20. Given that the standard potentials ((E^(@))) of CU^(2+)//Cu and CU^(+...

    Text Solution

    |