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Mole fraction of solvent in 0.2 m binary...

Mole fraction of solvent in 0.2 m binary aqueous solution of camphor (m = molality) is :

A

0.996

B

0.004

C

0.96

D

0.976

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The correct Answer is:
To find the mole fraction of the solvent (water) in a 0.2 m binary aqueous solution of camphor, we can follow these steps: ### Step 1: Understand the Definitions - **Molality (m)** is defined as the number of moles of solute per kilogram of solvent. - **Mole fraction (X)** of a component is defined as the number of moles of that component divided by the total number of moles of all components in the solution. ### Step 2: Identify the Given Data - We have a binary solution of camphor (solute) and water (solvent). - The molality of the solution is given as 0.2 m. ### Step 3: Calculate Moles of Solute - Since molality (m) = moles of solute / mass of solvent (kg), we can assume: - Moles of camphor (solute) = 0.2 moles (as we can take 1 kg of solvent for simplicity). ### Step 4: Calculate Mass of Solvent - We are assuming 1 kg of water (solvent), which is equivalent to 1000 grams. ### Step 5: Calculate Moles of Solvent - The molar mass of water (H2O) is approximately 18 g/mol. - Moles of water = mass of water (g) / molar mass of water (g/mol) \[ \text{Moles of water} = \frac{1000 \text{ g}}{18 \text{ g/mol}} \approx 55.56 \text{ moles} \] ### Step 6: Calculate Total Moles in the Solution - Total moles = moles of solute (camphor) + moles of solvent (water) \[ \text{Total moles} = 0.2 + 55.56 \approx 55.76 \text{ moles} \] ### Step 7: Calculate Mole Fraction of Solvent - The mole fraction of the solvent (water) is given by: \[ X_{\text{water}} = \frac{\text{moles of water}}{\text{total moles}} = \frac{55.56}{55.76} \approx 0.996 \] ### Final Answer The mole fraction of the solvent (water) in the 0.2 m binary aqueous solution of camphor is approximately **0.996**. ---
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