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In the conversion NH(2)OH rarr N(2)O, th...

In the conversion `NH_(2)OH rarr N_(2)O`, the equivalent weight of `NH_(2)OH` will be:

A

M

B

M/2

C

M/4

D

M/5

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The correct Answer is:
To find the equivalent weight of NH₂OH (hydroxylamine) in the conversion to N₂O (nitrous oxide), we can follow these steps: ### Step 1: Determine the oxidation states of nitrogen in both compounds. - In NH₂OH, let the oxidation state of nitrogen be \( x \). - The oxidation state of hydrogen is +1, and that of oxygen is -2. - The equation for the oxidation state in NH₂OH can be set up as: \[ x + 2(+1) + (-2) = 0 \] Simplifying this gives: \[ x + 2 - 2 = 0 \implies x = -1 \] - In N₂O, let the oxidation state of nitrogen be \( y \). - There are two nitrogen atoms and one oxygen atom, so the equation is: \[ 2y + (-2) = 0 \] Simplifying this gives: \[ 2y - 2 = 0 \implies 2y = 2 \implies y = +1 \] ### Step 2: Calculate the change in oxidation state. - The change in oxidation state from NH₂OH to N₂O is: \[ \Delta = y - x = 1 - (-1) = 1 + 1 = 2 \] ### Step 3: Calculate the equivalent weight. - The equivalent weight is given by the formula: \[ \text{Equivalent weight} = \frac{\text{Molecular weight}}{\text{n}} \] where \( n \) is the change in oxidation state (which we found to be 2). ### Step 4: Substitute the values into the formula. - Let the molecular weight of NH₂OH be \( m \). Then: \[ \text{Equivalent weight} = \frac{m}{2} \] ### Conclusion Thus, the equivalent weight of NH₂OH in the conversion to N₂O is \( \frac{m}{2} \).
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