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A solid is made of two element X and Z ....

A solid is made of two element `X` and `Z` .The atoms `Z` are in `C CP` arrangement while the atoms `X` occupy all the terahedral sites .What is the formula of the compound ?

A

XZ

B

`X_(2)Z`

C

`X_(2)Z_(3)`

D

`XZ_(2)`

Text Solution

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The correct Answer is:
To find the formula of the compound formed by elements X and Z, we need to analyze the arrangement of the atoms and the number of sites occupied by each element. ### Step-by-Step Solution: 1. **Identify the arrangement of atoms:** - The atoms of element Z are arranged in a Close Packed Cubic (CCP) structure. 2. **Determine the number of Z atoms in the unit cell:** - In a CCP arrangement, the number of atoms per unit cell is 4. This is because: - There are 8 corner atoms (each contributes 1/8 to the unit cell) and 6 face-centered atoms (each contributes 1/2 to the unit cell). - Therefore, the total number of atoms = \(8 \times \frac{1}{8} + 6 \times \frac{1}{2} = 1 + 3 = 4\). - Thus, \(Z = 4\). 3. **Identify the tetrahedral sites:** - In a CCP structure, the number of tetrahedral sites is twice the number of octahedral sites. - There are 4 octahedral sites in a CCP unit cell, hence the number of tetrahedral sites = \(2 \times 4 = 8\). 4. **Determine the number of X atoms:** - Since the atoms of element X occupy all the tetrahedral sites, the number of X atoms = 8. 5. **Find the ratio of X to Z:** - We have \(Z = 4\) and \(X = 8\). - The simplest whole number ratio of Z to X is \(4:8\), which simplifies to \(1:2\). 6. **Write the formula of the compound:** - Based on the ratio, the formula can be expressed as \(ZX_2\) or \(Z_1X_2\). - Therefore, the formula of the compound is \(XZ_2\). ### Final Answer: The formula of the compound is \(XZ_2\).
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