Home
Class 12
CHEMISTRY
Example of unit cell with crystallograph...

Example of unit cell with crystallographic dimensions
`a!=b!=c, alpha=beta=gamma=90^(@)` is :

A

Calcite

B

Graphite

C

Rhombic sulphur

D

Monoclinic sulphur

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the example of a unit cell with crystallographic dimensions where \( a \neq b \neq c \) and \( \alpha = \beta = \gamma = 90^\circ \), we will analyze the provided options step by step. ### Step 1: Understand the given conditions The conditions specify that: - The lengths of the edges of the unit cell are not equal: \( a \neq b \neq c \). - All the angles between the edges are right angles: \( \alpha = \beta = \gamma = 90^\circ \). ### Step 2: Analyze the options 1. **Calcite**: - Calcite is a rhombohedral structure where all edge lengths are equal (\( a = b = c \)) and all angles are equal to 90 degrees. - **Conclusion**: This option does not satisfy the conditions. 2. **Graphite**: - Graphite has a hexagonal structure where \( a = b \) but \( b \neq c \), and the angles are \( \alpha = \beta = 90^\circ \) and \( \gamma = 120^\circ \). - **Conclusion**: This option does not satisfy the conditions. 3. **Rhombic Sulphur**: - Rhombic sulphur is an example of an orthorhombic structure where \( a \neq b \neq c \) and \( \alpha = \beta = \gamma = 90^\circ \). - **Conclusion**: This option satisfies all the conditions. 4. **Monoclinic Sulphur**: - Monoclinic structures have \( a \neq b \neq c \) but \( \beta \) is not equal to 90 degrees (it is typically greater or less than 90 degrees). - **Conclusion**: This option does not satisfy the conditions. ### Step 3: Final Conclusion Based on the analysis of the options, the only unit cell that fits the criteria of \( a \neq b \neq c \) and \( \alpha = \beta = \gamma = 90^\circ \) is **Rhombic Sulphur**. ### Answer: The example of a unit cell with crystallographic dimensions \( a \neq b \neq c \) and \( \alpha = \beta = \gamma = 90^\circ \) is **Rhombic Sulphur**. ---
Promotional Banner

Topper's Solved these Questions

  • THE SOLID STATE

    VMC MODULES ENGLISH|Exercise EFFICIENT|50 Videos
  • THE SOLID STATE

    VMC MODULES ENGLISH|Exercise IMPECCABLE|49 Videos
  • THE SOLID STATE

    VMC MODULES ENGLISH|Exercise FUNDAMENTAL|50 Videos
  • SURFACE CHEMISTRY

    VMC MODULES ENGLISH|Exercise PRACTICE EXERCISE|9 Videos
  • THEORY OF SOLUTIONS

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|31 Videos

Similar Questions

Explore conceptually related problems

Example of unit cell with crystallographic dimensions anebnec,alpha=gamma=90^(@),betane90^(@) is

The unit cell with crystallographic dimensions , a= b nec " and " alpha = beta=gamma = 90^0

The unit cell with crystallographic dimensions, a ne b ne c, alpha =gamma=90^(@) and beta ne 90^(@) is :

The crystal system for which a!= b!= c and alpha = beta = gamma = 90^(@) is said to be

The crystal system of a compound with unit cell dimensions a=0.387,b=0.387 and c=0.504 and alpha=beta=90^(@) and gamma=120^(@) is

The crystal system of a compound with unit cell dimensions a=0.350,b=0.350 and c=0.500 and alpha=beta=90^(@) and gamma=120^(@) is

The regular three dimensional arrangement of points in a crystal is known as crystal lattice and the smallest repeating pattern in the lattice is called unit cell. The unit cells are characterised by the edge lengths a, b, c and the angles between them alpha, beta and gamma respectively. Based on this, there are seven crystal systems. In a cubic unit cell: a=b=c and alpha = beta=gamma=90^(@) The number of points in simple, body centred and face centred cubic cells are 1,2 and 4 respectively In both the hcp and ccp of spheres, the number of tetrahedral voids per sphere is two while the octahedral voids is one. In a face centred cubic cell, an atom at the face contributes to the unit cell

The regular three dimensional arrangement of points in a crystal is known as crystal lattice and the smallest repeating pattern in the lattice is called unit cell. The unit cells are characterised by the edge lengths a, b, c and the angles between them alpha, beta and gamma respectively. Based on this, there are seven crystal systems. In a cubic unit cell: a=b=c and alpha = beta=gamma=90^(@) The number of points in simple, body centred and face centred cubic cells are 1,2 and 4 respectively In both the hcp and ccp of spheres, the number of tetrahedral voids per sphere is two while the octahedral voids is one. The C.N of cation occuppying an octahedral vois is:

The regular three dimensional arrangement of points in a crystal is known as crystal lattice and the smallest repeating pattern in the lattice is called unit cell. The unit cells are characterised by the edge lengths a, b, c and the angles between them alpha, beta and gamma respectively. Based on this, there are seven crystal systems. In a cubic unit cell: a=b=c and alpha = beta=gamma=90^(@) The number of points in simple, body centred and face centred cubic cells are 1,2 and 4 respectively In both the hcp and ccp of spheres, the number of tetrahedral voids per sphere is two while the octahedral voids is one. A double triangular void surrounded by three spheres above and three spheres below is called

The following diagram shows the arrangement of lattice points with a = b = c and alpha = beta = gamma = 90^(@) . Choose the correct options.

VMC MODULES ENGLISH-THE SOLID STATE-ENABLE
  1. The number of unit cells in 58.5 g of NaCl is nearly

    Text Solution

    |

  2. How many Cl^(-) ions are there around Na^(+)ion in NaCl crystal ?

    Text Solution

    |

  3. Example of unit cell with crystallographic dimensions a!=b!=c, alph...

    Text Solution

    |

  4. Pick up the correct statement: (a) The crystal of AgBr does not have...

    Text Solution

    |

  5. The edge length of a face-centred cubic unit cell is 508 p m. If the r...

    Text Solution

    |

  6. A solid has a structure in which W atoms are located at the corners of...

    Text Solution

    |

  7. If we mix a pentavalent impurity in a crystal lattice of germanium, wh...

    Text Solution

    |

  8. In the crystals structures of sodium chloride, the arrangement of Cl^(...

    Text Solution

    |

  9. Mercury is the only metal which is liquid at 0^@C this is due to its

    Text Solution

    |

  10. Which of the following describes the hexagonal close packed arrangemen...

    Text Solution

    |

  11. An element having bcc structure has 12.8xx10^(23) unit cells. The numb...

    Text Solution

    |

  12. The maximum proportion of available volume that can be filled by hard ...

    Text Solution

    |

  13. A compound is formed by elements A and B. This crystallises in the cub...

    Text Solution

    |

  14. Tetragonal crystal system has the following unit cell dimensions.

    Text Solution

    |

  15. A metallic element has a cubic lattice. Each edge of the unit cell is ...

    Text Solution

    |

  16. In a crystal, the atoms are located at the position of

    Text Solution

    |

  17. Sodium metal crystallizes in body centred cubic lattice with the cell ...

    Text Solution

    |

  18. Metallic gold crystallizes in the face centered cubic lattice. What is...

    Text Solution

    |

  19. Which of the following expression is correct in case of a sodium chlor...

    Text Solution

    |

  20. The edge length of sodium chloride unit cell is 564 pm. If the size of...

    Text Solution

    |