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Ethylamine when treated with acetyl ...

Ethylamine when treated with acetyl chloride we get a compound of the formula .

A

`CH_3 - underset(O ) underset( ||) C-underset( CH_3) underset(|) N-NH -C_2H_5`

B

`C_2H_5 -underset(O) underset(||) C-NH -C_2 H_5`

C

`CH_3-underset(O) underset( ||)C- underset(H) underset(|) N-CH_2 -CH_3`

D

`CH_3 -underset(O) underset(||)C- underset(H) underset(|) N-underset(CH_3 ) underset( |) CH -CH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To find the compound formed when ethylamine is treated with acetyl chloride, we can follow these steps: ### Step 1: Identify the Reactants - Ethylamine has the formula **C2H5NH2** (or **CH3CH2NH2**). - Acetyl chloride has the formula **CH3COCl**. ### Step 2: Understand the Reaction Mechanism - Ethylamine contains a nitrogen atom with a lone pair of electrons, which makes it a nucleophile. - Acetyl chloride has a carbonyl group (C=O) that is electrophilic due to the partial positive charge on the carbon atom (due to the electronegativity of oxygen). ### Step 3: Nucleophilic Attack - The lone pair on the nitrogen atom of ethylamine attacks the electrophilic carbon atom of acetyl chloride. - This results in the formation of a tetrahedral intermediate. ### Step 4: Formation of the Product - The tetrahedral intermediate collapses, leading to the elimination of a chloride ion (Cl-), which is a good leaving group. - This results in the formation of an amide. ### Step 5: Write the Final Product - The product formed is **C2H5NHC(O)CH3**, which can also be written as **CH3C(O)NHC2H5**. - This compound is known as N-ethylacetamide. ### Final Answer The compound formed when ethylamine is treated with acetyl chloride is **C2H5NHC(O)CH3** or **N-ethylacetamide**. ---
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  • When salicylic acid is treated with acetic anhydride, we get :

    A
    aspirin
    B
    paracetamol
    C
    salol
    D
    none of the above
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