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Mendius reaction converts an alkyl cyani...

Mendius reaction converts an alkyl cyanide to"

A

`Zn-Hg //HCI`

B

`SnCl_2 //HCI`

C

`Na//C_2H_5 OH`

D

`LiAlH_4`

Text Solution

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The correct Answer is:
**Step-by-Step Solution:** 1. **Understanding the Mendis Reaction:** - The Mendis reaction is a chemical reaction that involves the reduction of nitriles to primary amines. Nitriles are compounds that contain a carbon atom triple-bonded to a nitrogen atom (R-C≡N). 2. **Formation of Nitriles:** - Nitriles can be formed from amides through a dehydration process. For example, when an amide (R-C(O)NH2) is heated in the presence of phosphorus pentoxide (P4O10), it loses a water molecule and converts into a nitrile (R-C≡N). 3. **Reduction of Nitriles:** - The reduction of nitriles to primary amines is achieved by reacting the nitrile with sodium in the presence of an alcohol, typically ethanol. The general reaction can be represented as: \[ R-C≡N + 2 \text{[H]} \xrightarrow{\text{Na, EtOH}} R-CH2-NH2 \] - Here, the nitrile (R-C≡N) is reduced to a primary amine (R-CH2-NH2). 4. **Identifying the Correct Answer:** - The question asks what the Mendis reaction converts an alkyl cyanide to. Based on the above understanding, we conclude that the Mendis reaction converts an alkyl cyanide (which is a type of nitrile) to a primary amine. 5. **Conclusion:** - Therefore, the Mendis reaction converts an alkyl cyanide to a primary amine. ---
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