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Nitrobenzene can be converted into hydra...

Nitrobenzene can be converted into hydraxobenzene by reduction with

A

`Zn //NaOH`

B

`Zn//" sodium amalgam"`

C

`Al//Hg`

D

`Sn //HCI`

Text Solution

AI Generated Solution

The correct Answer is:
To convert nitrobenzene into hydrazobenzene through reduction, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The starting compound is nitrobenzene (C6H5NO2), which contains a nitro group (-NO2) attached to a benzene ring. 2. **Understand the Target Product**: - The target compound is hydrazobenzene (C6H4(N2H2)), which has two nitrogen atoms connected by a single bond (hydrazine structure) attached to the benzene ring. 3. **Select the Reducing Agent**: - To reduce nitrobenzene to hydrazobenzene, we need a suitable reducing agent. The options provided include various reagents. 4. **Evaluate the Options**: - **Option A: Zinc in the presence of Sodium Hydroxide (NaOH)**: This combination is known to effectively reduce nitro compounds to hydrazines. Therefore, this is a suitable choice. - **Option B: Zinc Sodium Amalgam**: This reagent is typically used in Clemenson reduction and would not yield hydrazobenzene. - **Option C: Sn/HCl**: This combination would reduce nitrobenzene to aniline (C6H5NH2), not hydrazobenzene. - **Option D: Aluminum and Mercury**: Similar to Sn/HCl, this would also reduce nitrobenzene to aniline, not hydrazobenzene. 5. **Conclusion**: - The correct reducing agent for converting nitrobenzene to hydrazobenzene is **Zinc in the presence of Sodium Hydroxide (NaOH)**. ### Final Answer: The correct answer is **A: Zinc in the presence of Sodium Hydroxide (NaOH)**. ---
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