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[A] + [B ] to C2 H5 NH CONHC2 H5 ...

`[A] + [B ] to C_2 H_5 NH CONHC_2 H_5 `
`{:( (a ) COCl_2 , (b ) ALCl_3),(( c ) C_2 H_5 NH_2 , (d) CH_2 Br_2 ):}`
here , [A] & [B] are

A

a,b

B

b,c

C

c,d

D

a,c

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the reactants [A] and [B] that lead to the formation of the product \( C_2H_5NHCONHC_2H_5 \). Let's analyze the given options step by step. ### Step 1: Analyze the Product Structure The product \( C_2H_5NHCONHC_2H_5 \) contains: - A carbonyl group (C=O) - Two ethylamine groups (C2H5NH) This suggests that one reactant must provide the carbonyl group, while the other must provide the amine groups. ### Step 2: Identify the Reactants Let's look at the given options: 1. **(a) COCl2** - This compound contains a carbonyl group (C=O) and is known as thionyl chloride. It can react to form an amide. 2. **(b) AlCl3** - This is a Lewis acid and does not provide a carbonyl or amine group. 3. **(c) C2H5NH2** - This is ethylamine and contains the amine group. 4. **(d) CH2Br2** - This compound does not contain a carbonyl or amine group. From this analysis, we can conclude: - **[A] = COCl2** (provides the carbonyl group) - **[B] = C2H5NH2** (provides the amine groups) ### Step 3: Reaction Mechanism 1. **Formation of the Intermediate:** - Ethylamine \( C_2H_5NH_2 \) attacks the carbonyl carbon of \( COCl_2 \), forming an intermediate where the Cl is displaced. - The structure at this point is \( C_2H_5NH-C(=O)Cl \). 2. **Formation of the Final Product:** - Another molecule of ethylamine attacks the carbonyl carbon, leading to the formation of the amide bond. - The final product is \( C_2H_5NHCONHC_2H_5 \). ### Conclusion Thus, the correct reactants [A] and [B] are: - **[A] = COCl2** - **[B] = C2H5NH2** ### Final Answer The correct option is (a) COCl2 and (c) C2H5NH2. ---
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