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In the reaction : CH3 MgCl + NH3 to ...

In the reaction `: CH_3 MgCl + NH_3 to ? ` The product is :

A

`CH_3NH_2`

B

`CH_4`

C

`CH_3MgNH_2`

D

`CH_3Cl`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the reaction of CH₃MgCl with NH₃, we can follow these steps: ### Step 1: Identify the Reactants The reactants in the reaction are CH₃MgCl (a Grignard reagent) and NH₃ (ammonia). ### Step 2: Understand the Nature of the Grignard Reagent CH₃MgCl is a Grignard reagent. In this compound, the carbon (C) in CH₃ has a partial negative charge (δ-) due to the electronegativity difference between carbon and magnesium. The magnesium (Mg) has a partial positive charge (δ+). ### Step 3: Recognize the Acidity of Ammonia In ammonia (NH₃), the hydrogen atoms attached to nitrogen are considered acidic hydrogens because nitrogen is electronegative and can stabilize the negative charge when it loses a hydrogen ion (H⁺). ### Step 4: Reaction Mechanism The CH₃⁻ (from CH₃MgCl) will act as a nucleophile and attack one of the acidic hydrogens (H⁺) from NH₃. This results in the formation of methane (CH₄) and a negatively charged amide ion (NH₂⁻). ### Step 5: Formation of Products The reaction produces: 1. Methane (CH₄) 2. The magnesium ion (Mg²⁺) combines with the amide ion (NH₂⁻) to form magnesium amide chloride (MgNH₂Cl). ### Final Products Thus, the final products of the reaction are: - CH₄ (methane) - MgNH₂Cl (magnesium amide chloride) ### Conclusion The correct answer to the question is CH₄ (methane). ---
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