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CH3 CN overset( Na // EtOH ) to X. ...

`CH_3 CN overset( Na // EtOH ) to X.` the compound X is

A

`CH_3 CONH_2`

B

`CH_3 CH_2 NH_2`

C

`C_2 H_6`

D

`CH_3 NHCH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question `CH₃CN overset(Na // EtOH) to X`, we will break down the reaction step by step. ### Step 1: Identify the Reactants The reactant is acetonitrile (CH₃CN), which contains a carbon (C) atom bonded to a nitrogen (N) atom. ### Step 2: Understand the Role of Sodium (Na) and Ethanol (EtOH) In this reaction, sodium (Na) acts as a reducing agent, providing electrons to the acetonitrile. Ethanol (EtOH) serves as a proton donor, supplying protons (H⁺) during the reaction. ### Step 3: Mechanism of the Reaction 1. **Formation of a Carbanion**: The nitrogen in acetonitrile is more electronegative, which leads to polarization of the C≡N bond. When sodium donates electrons, a carbanion is formed: \[ CH₃C \equiv N + 2Na \rightarrow CH₃C \equiv N^{-} + 2Na^{+} \] 2. **Nucleophilic Attack**: The carbanion can attack the proton (H⁺) from ethanol. This results in the formation of a double bond between carbon and nitrogen: \[ CH₃C^{-} + H^{+} \rightarrow CH₃C=N \] 3. **Protonation of Nitrogen**: The nitrogen atom, now negatively charged, abstracts another proton from ethanol: \[ CH₃C=N^{-} + H^{+} \rightarrow CH₃CH_{2}NH_{2} \] ### Step 4: Identify the Product X The final product after the reaction is a primary amine, specifically ethylamine (CH₃CH₂NH₂). ### Conclusion Thus, the compound X formed from the reaction of acetonitrile with sodium in the presence of ethanol is **ethylamine (CH₃CH₂NH₂)**. ---
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