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C(6)H(5)NH(2) + CS(2) underset(KOH (s))o...

`C_(6)H_(5)NH_(2) + CS_(2) underset(KOH (s))overset(Delta)rarr`
The end product in the reaction is

A

Phenyl cyanide

B

Phenyl isocyanide

C

Phenyl isothiocyanate

D

p-Amino benzene sulphonic acid

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of aniline (C₆H₅NH₂) with carbon disulfide (CS₂) in the presence of potassium hydroxide (KOH) and heat, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants are aniline (C₆H₅NH₂) and carbon disulfide (CS₂). Aniline is an aromatic amine with a phenyl group attached to an amino group. 2. **Understand the Reaction Conditions**: The reaction occurs in the presence of potassium hydroxide (KOH) and is heated. KOH acts as a strong base, which will facilitate the reaction. 3. **Recognize the Type of Reaction**: This reaction is known as the mustard oil reaction, which typically involves the reaction of an amine with carbon disulfide to form isothiocyanates. 4. **Write the Reaction**: When aniline reacts with carbon disulfide in the presence of KOH, the following reaction occurs: \[ C₆H₅NH₂ + CS₂ \xrightarrow{KOH, \Delta} C₆H₅N=C=S + H₂O + K₂S \] Here, C₆H₅N=C=S is phenyl isothiocyanate. 5. **Identify the Product**: The product formed is phenyl isothiocyanate (C₆H₅N=C=S), which is characterized by the presence of a sulfur atom in the isothiocyanate functional group. 6. **Conclusion**: The end product of the reaction between aniline and carbon disulfide in the presence of KOH and heat is phenyl isothiocyanate. ### Final Answer: The end product of the reaction is **phenyl isothiocyanate**. ---
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