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The product of the reaction of ethyl iod...

The product of the reaction of ethyl iodide with Zn-Cu couple/alcohol can also be prepared by the following reaction.

A

By the hydrolysis of the product obtained from the reaction of ethyl iodide with Mg in dry ether.

B

Reaction of iodomethane with Na in dry ether

C

By the reduction of ethyl alcohol with red P + HI

D

All of the above

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The correct Answer is:
To solve the problem, we need to identify the product of the reaction of ethyl iodide (C2H5I) with a zinc-copper couple in alcohol and see how it can also be prepared through other reactions. ### Step-by-Step Solution: 1. **Identify the Reaction with Zinc-Copper Couple:** - Ethyl iodide (C2H5I) reacts with a zinc-copper couple in the presence of alcohol to produce ethane (C2H6). - The reaction can be represented as: \[ \text{C2H5I} + \text{Zn-Cu} \xrightarrow{\text{alcohol}} \text{C2H6} + \text{ZnI2} \] 2. **Option A - Hydrolysis of Product from Reaction with Magnesium:** - Ethyl iodide can also react with magnesium in dry ether to form a Grignard reagent (C2H5MgI). - Hydrolysis of this Grignard reagent with water or dilute acid will yield ethane: \[ \text{C2H5MgI} + \text{H2O} \rightarrow \text{C2H6} + \text{Mg(OH)I} \] - Thus, option A is valid. 3. **Option B - Reaction of Iodomethane with Sodium in Dry Ether:** - Iodomethane (CH3I) can react with sodium in dry ether to form a Grignard reagent (CH3Na). - When this Grignard reagent reacts with ethyl iodide (C2H5I), it forms ethane: \[ \text{CH3Na} + \text{C2H5I} \rightarrow \text{C2H6} + \text{NaI} \] - Therefore, option B is also valid. 4. **Option C - Reduction of Ethyl Alcohol with Red Phosphorus and HI:** - Ethyl alcohol (C2H5OH) can be reduced using red phosphorus and hydroiodic acid (HI) to produce ethane: \[ \text{C2H5OH} + \text{HI} \xrightarrow{\text{red P}} \text{C2H6} + \text{H2O} + \text{I2} \] - Hence, option C is valid as well. 5. **Conclusion:** - Since all options A, B, and C lead to the formation of ethane (C2H6), the correct answer is: \[ \text{D: All of the above} \]
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