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CH(3)-CH=CH(2)underset("Peroxide")overse...

`CH_(3)-CH=CH_(2)underset("Peroxide")overset(HBr)to[A]overset(KOH(aq))to[B]underset(443 K)overset(H_(2)SO_(4)(conc.))to[C]`

A

n –propanol

B

Isopropanol

C

Propane

D

Ethane

Text Solution

Verified by Experts

The correct Answer is:
D
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CH-=CHunderset(HgSO_(4)//H_(2)SO_(4))overset(H_(2)O)to[A]overset(LiAlH_(4)//H)to[B]underset(443 K)overset(H_(2)SO_(4)(conc.))to[C]

CH_(3)-CH=CH_(2)underset(773 K)overset(Br_(2))to[A]underset("Heat")overset(KOH(alc.))to[B]

CH_(3)CH_(2)OHunderset(443 K)overset(H_(2)SO_(4)(conc.))to[A]overset(H_(2)O //H^(+))to[B]overset(PCI_(5))to[C]

CH_(3)-underset(CH_(3)) underset(|) (C)= CH_(2) underset("Peroxide") overset(HBr)to CH_(3)-underset(CH_(3)) underset(|) (CH)-CH_(2)Br reaction intermediate of this reaction is:

When pinacol is treated with dilute H_(2)SO_(4) , a re-arangement reaction takes place which leads to the formation of a ketone. CH_(3)-underset(CH_(3))underset(|)overset(OH)overset(|)C-underset(CH_(3))underset(|)overset(OH)C-CH_(3)overset(H_(2)SO_(4))rarrCH_(3)-underset(CH_(3))underset(|)overset(O)overset(||)C-overset(CH_(3))overset(|)C-CH_(5) This reaction involves re-arrangement of carbocation Step 1: CH_(3)-underset(CH_(3))underset(|)overset(OH)overset(|)C-underset(CH_(3))overset(+)overset(OH_(2))overset(|)C-CH_(2)rarrCH_(3)-underset(CH_(3))underset(|)overset(OH)overset(|)C-underset(CH_(3))underset(|)overset(OH)overset(|)C-underset(CH_(3))underset(|)overset(+)C-CH_(3) Step 2: Carbocation rearrange by hydride, alkyl shift to get as stable as they can. Stability is the driving force for re-arrangement migration of bond may also oC Cur. Where by ring expansion and ring contraction takes place. The relief of strain can provide a powerful driving force for re-arrangement. What will be the product of following reaction R is:

When pinacol is treated with dilute H_(2)SO_(4) , a re-arangement reaction takes place which leads to the formation of a ketone. CH_(3)-underset(CH_(3))underset(|)overset(OH)overset(|)C-underset(CH_(3))underset(|)overset(OH)C-CH_(3)overset(H_(2)SO_(4))rarrCH_(3)-underset(CH_(3))underset(|)overset(O)overset(||)C-overset(CH_(3))overset(|)C-CH_(5) This reaction involves re-arrangement of carbocation Step 1: CH_(3)-underset(CH_(3))underset(|)overset(OH)overset(|)C-underset(CH_(3))overset(+)overset(OH_(2))overset(|)C-CH_(2)rarrCH_(3)-underset(CH_(3))underset(|)overset(OH)overset(|)C-underset(CH_(3))underset(|)overset(OH)overset(|)C-underset(CH_(3))underset(|)overset(+)C-CH_(3) Step 2: Carbocation rearrange by hydride, alkyl shift to get as stable as they can. Stability is the driving force for re-arrangement migration of bond may also oC Cur. Where by ring expansion and ring contraction takes place. The relief of strain can provide a powerful driving force for re-arrangement. What will be the product of following reaction

The IUPAC name of following compound is: CH_(3)CH_(2) - underset(CH_(3))underset(|)overset(H)overset(|)(C) - underset(CH_(3))underset(|)overset(C_(4)H_(9))overset(|)(C) - CH_(3)

VMC MODULES ENGLISH-HALOALKANES & HALOARENES -ENABLE
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  4. A overset(Cl(2))(rarr) B overset("AgCN")(rarr) C overset([H])(rarr) (C...

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