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CH 3 ​ −CH 2 ​ −Br Alco.KOH Δ ​ B ...

CH 3 ​ −CH 2 ​ −Br Alco.KOH Δ ​ B HBr ​ C Na/ether ​ D the compound D is

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To solve the question step by step, let's break down the reactions involving the compound CH₃-CH₂-Br. ### Step 1: Reaction with Alcoholic KOH The first step involves the reaction of CH₃-CH₂-Br with alcoholic KOH under heat (Δ). Alcoholic KOH promotes elimination reactions. Here, the bromine (Br) will be eliminated along with a hydrogen atom (H) from the adjacent carbon, leading to the formation of an alkene. **Reaction:** \[ \text{CH}_3\text{-CH}_2\text{-Br} + \text{Alco. KOH} \xrightarrow{\Delta} \text{CH}_3\text{-CH}=\text{CH}_2 + \text{HBr} \] **Product:** The product formed is propene (CH₃-CH=CH₂). ### Step 2: Reaction with HBr Next, the alkene (propene) reacts with HBr. This is an electrophilic addition reaction where HBr adds across the double bond. The bromine will add to one of the carbons of the double bond, and a hydrogen will add to the other. **Reaction:** \[ \text{CH}_3\text{-CH}=\text{CH}_2 + \text{HBr} \rightarrow \text{CH}_3\text{-CH}_2\text{-Br} \] **Product:** The product formed is again bromoethane (CH₃-CH₂-Br). ### Step 3: Reaction with Sodium in Ether (Wurtz Reaction) Finally, the bromoethane undergoes a Wurtz reaction when treated with sodium in ether. In this reaction, two alkyl halides couple to form a new alkane. **Reaction:** \[ 2 \text{CH}_3\text{-CH}_2\text{-Br} + 2 \text{Na} \xrightarrow{\text{Ether}} \text{CH}_3\text{-CH}_2\text{-CH}_2\text{-CH}_3 + 2 \text{NaBr} \] **Product:** The product formed is butane (CH₃-CH₂-CH₂-CH₃). ### Final Answer The compound D is butane (C₄H₁₀). ---
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VMC MODULES ENGLISH-HALOALKANES & HALOARENES -ENABLE
  1. In the reaction CH(3)C equiv C^(-)Na^(+) + (CH(3))(2) CHCl rarr Prod...

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  2. The reaction shows which of the following mechanisms? CH(3) - under...

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  3. CH 3 ​ −CH 2 ​ −Br Alco.KOH Δ ​ B HBr ​ C Na/ether ​ D the c...

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  4. In the following sequence of reactions, CH(3)CH(2)CH(2)Br overset("K...

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  5. The structural formula of the compound which yields ethylene upon rea...

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  6. Germinal dihalides on hydrolysis give

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  7. Which of the following on treating with zinc gives 2–butene?

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  8. Ethylidene chloride on treatement with aq. KOH gives

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  9. Acetone reacts with phosphorous pentachloride to give:

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  10. Which of the following is used as an insecticide?

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  11. Which would be obtained by boiling CHCl3 with dilute KOH?

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  12. On reacting chloral hydrate with NaOH the products obtained is/are:

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  13. Which statement is wrong about chloroform?

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  14. The formula of freon -12 is :

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  15. Which of the following alkyl halides on hydrolysis gives a glycol?

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  16. The primary product of hydrolysis of CH(3)I is:

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  17. Butane nitrile can be prepared by heating

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  18. Which of the following reactions of C2H5Br does not represent an examp...

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  19. Amongst the following, which are true for S(N^2) reaction ? (i) The ra...

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  20. The unsaturated hydrocarbon obtained by the reaction of a dihalogen de...

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