Home
Class 12
CHEMISTRY
What is the final product of the followi...

What is the final product of the following reaction?
`CH_(3) CH = CH_(2) + NBS rarr " A " overset("AgCN")(rarr)`B (Major)

A

`CH_(3)`CH =CHCN

B

`CH_(3) `CH = CHNC

C

`CH_(2) = CHCH_(2)`CN

D

`CH_(2) = CHCH_(2)`NC

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the final product of the reaction involving `CH3CH=CH2` with N-bromosuccinimide (NBS) followed by treatment with silver cyanide (AgCN), we can break it down into steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The starting compound is `CH3CH=CH2`, which is propene. The reagents involved are N-bromosuccinimide (NBS) and silver cyanide (AgCN). **Hint**: Recognize the structure of the alkene and the reagents involved. 2. **Reaction with NBS**: NBS is used for allylic bromination. In this reaction, the hydrogen atom on the carbon adjacent to the double bond (the allylic position) will be replaced by a bromine atom. - The allylic carbon in propene is the one next to the double bond, which is `CH2` in `CH3-CH=CH2`. - The product of this reaction (let's call it Product A) will be `CH3-CHBr-CH2`. **Hint**: Remember that NBS selectively brominates the allylic position. 3. **Formation of Product A**: The product A can be represented as: \[ \text{A} = CH3-CHBr-CH2 \] **Hint**: Write down the structure of Product A to visualize the bromination. 4. **Reaction with AgCN**: Next, we treat Product A with silver cyanide (AgCN). AgCN dissociates into Ag+ and CN-. The bromine atom in Product A is a good leaving group due to its electronegativity. - The CN- ion acts as a nucleophile and attacks the carbon atom bonded to bromine, leading to the substitution of bromine with the cyanide group. 5. **Formation of Product B**: The final product (let's call it Product B) will be: \[ \text{B} = CH3-CH(CN)-CH2 \] This structure can also be written as: \[ \text{B} = CH2=CH-CH2-CN \] However, the major product will be the one where the cyanide is attached to the allylic carbon. **Hint**: Identify the major product by considering the stability of the resulting structure. ### Final Answer: The final product of the reaction is: \[ \text{B} = CH3-CH(CN)-CH2 \]
Promotional Banner

Topper's Solved these Questions

  • HALOALKANES & HALOARENES

    VMC MODULES ENGLISH|Exercise EFFICIENT|100 Videos
  • ENVIRONMENTAL CHEMISTRY

    VMC MODULES ENGLISH|Exercise JEE Main (Archive)|39 Videos
  • HALOALKANES AND HALOARENES

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE - F|6 Videos

Similar Questions

Explore conceptually related problems

Write the product of the following reaction : CH_(2)=CH-CH_(2)-OH overset(PC C)(rarr)

The major product of the following reaction is : CH_(3)CH=CHCO_(2)CH_(3)overset(LiAlH_(4))rarr

major product of the following reaction is : CH_(3)CH=CHCO_(2)CH_(3) overset("LiAIH"_(4))rarr

Write the final product of the following reaction : CH_(3)-underset(OH)underset(|)(CH)-CH_(3) overset(Cu//573 K)(rarr)

What are the major products formed in the following reactions ? (i) C_(6)H_(5)-CH_(2)-CH=CH_(2)+HBr rarr (ii)

Identifity the product of following reaction : CH_(3)CH_(2)CH_(2)Ioverset("KOH(alc)")rarr[A]

What will be product in the following reaction CH_(3)-CH_(2)-CH_(2)-CH_(3)overset(KMnO_(4))rarr ?

Identify the final product in that follow sequence of reactions. CH_(2)=CH_(2)overset(Br_(2))rarr(X)overset(KCN)rarr (Y) overset(H_(3)O^(+))rarr (Z)

The major product of the following reaction is : CH_(3)C-=CH overset((i)DCl(1 "equiv".))underset((ii)DI)rarr

VMC MODULES ENGLISH-HALOALKANES & HALOARENES -IMPECCABLE
  1. Iodoform test is not given by:

    Text Solution

    |

  2. In the laboratory, chloroform is prepared by which of the following me...

    Text Solution

    |

  3. What is the final product of the following reaction? CH(3) CH = CH(...

    Text Solution

    |

  4. 1,2 di-bromo cyclohexane on dehydro halogenation give:-

    Text Solution

    |

  5. Wurtz reaction of methyl iodide yields an organic compound X. Which on...

    Text Solution

    |

  6. In the reaction C(2)H(5)MgBr +

    Text Solution

    |

  7. Which one will give positive iodoform test?

    Text Solution

    |

  8. War gas is formed from:

    Text Solution

    |

  9. C(2) H(5) Cl + KCN rarr "X " overset("Hydroysis")(rarr) Y, 'X' and 'Y'...

    Text Solution

    |

  10. Iodoform is formed on warming I2 and NaOH with:

    Text Solution

    |

  11. Carbon-halogen bond is strongest among the following:

    Text Solution

    |

  12. Compound A has a molecular formula C(2)Cl(3)OH. It reduces Fehling's s...

    Text Solution

    |

  13. For a given alkyl group the densities of the halides follow the order:

    Text Solution

    |

  14. "AgNO"(3) does not give precipitate with chloroform because:

    Text Solution

    |

  15. Which of the following alkyl halides is iso -butyl bromide ?

    Text Solution

    |

  16. In which one of the following conversions phosphorus pentachloride is ...

    Text Solution

    |

  17. An organic halide is shaken with aqueous NaOH followed by the addition...

    Text Solution

    |

  18. In which alkyl halide S(N)2 mechanism is favoured maximum?

    Text Solution

    |

  19. The reaction of tertiary butyl bromide with sodium methoxide gi...

    Text Solution

    |

  20. When alkyl halides are heated with dry Ag(2)O, it gives:

    Text Solution

    |