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CH(3)"COOH" underset(Br(2))overset("AgOH...

`CH_(3)"COOH" underset(Br_(2))overset("AgOH")(rarr)"[A]" overset("AgCN")` [B] `overset("HOH")(rarr)` [ C] + [D], in reaction [C] & [D] are

A

`(CH_(3))_(2) NH + H_(2)`O

B

`(CH_(3))_(2)` NH + HCOOH

C

`CH_(3)NH_(2) + ` HCOOH

D

`CH_(3)"COOH" + NH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reaction step by step, we will analyze the transformations occurring in the reaction sequence. The reaction involves acetic acid (CH₃COOH), bromine (Br₂), silver hydroxide (AgOH), and silver cyanide (AgCN), leading to the formation of compounds A, B, C, and D. ### Step 1: Reaction of Acetic Acid with Bromine and Silver Hydroxide 1. **Starting Compound**: Acetic acid (CH₃COOH). 2. **Reagents**: Br₂ and AgOH. 3. **Reaction**: The bromine reacts with acetic acid in the presence of silver hydroxide, leading to the formation of bromoacetic acid (CH₂BrCOOH) and the removal of silver bromide (AgBr) as a byproduct. **Chemical Equation**: \[ \text{CH}_3\text{COOH} + \text{Br}_2 + \text{AgOH} \rightarrow \text{CH}_2\text{BrCOOH} + \text{AgBr} + \text{H}_2\text{O} \] **Compound A**: Bromoacetic acid (CH₂BrCOOH). ### Step 2: Reaction of Compound A with Silver Cyanide 1. **Compound A**: Bromoacetic acid (CH₂BrCOOH). 2. **Reagent**: AgCN. 3. **Reaction**: Bromoacetic acid reacts with silver cyanide, replacing the bromine atom with a cyanide group, forming cyanoacetic acid (CH₂(CN)COOH) and precipitating silver bromide. **Chemical Equation**: \[ \text{CH}_2\text{BrCOOH} + \text{AgCN} \rightarrow \text{CH}_2(\text{CN})\text{COOH} + \text{AgBr} \] **Compound B**: Cyanoacetic acid (CH₂(CN)COOH). ### Step 3: Hydrolysis of Compound B 1. **Compound B**: Cyanoacetic acid (CH₂(CN)COOH). 2. **Reagent**: Water (H₂O). 3. **Reaction**: Hydrolysis of cyanoacetic acid leads to the formation of acetic acid (CH₃COOH) and ammonia (NH₃) as the cyanide group is converted into an amine. **Chemical Equation**: \[ \text{CH}_2(\text{CN})\text{COOH} + 2\text{H}_2\text{O} \rightarrow \text{CH}_3\text{COOH} + \text{NH}_3 + \text{CO}_2 \] **Compounds C and D**: - Compound C: Acetic acid (CH₃COOH). - Compound D: Ammonia (NH₃). ### Final Summary - **Compound A**: Bromoacetic acid (CH₂BrCOOH). - **Compound B**: Cyanoacetic acid (CH₂(CN)COOH). - **Compound C**: Acetic acid (CH₃COOH). - **Compound D**: Ammonia (NH₃). ### Answer: The compounds C and D are acetic acid (CH₃COOH) and ammonia (NH₃), respectively. ---
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VMC MODULES ENGLISH-HALOALKANES & HALOARENES -ENABLE
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  2. The reaction shows which of the following mechanisms? CH(3) - under...

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  3. CH(3)"COOH" underset(Br(2))overset("AgOH")(rarr)"[A]" overset("AgCN") ...

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  4. In the following sequence of reactions, CH(3)CH(2)CH(2)Br overset("K...

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  5. The structural formula of the compound which yields ethylene upon rea...

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  6. Gem dihalides on hydrolysis give:

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  7. Which of the following on treating with zinc gives 2–butene?

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  8. Ethylidene chloride reacts with eq. KOH to form which of the following...

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  9. Acetone reacts with phosphorous pentachloride to give:

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  10. Which of the following is used as an insecticide?

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  11. Which would be obtained by boiling CHCl3 with dilute KOH?

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  12. On reacting chloral hydrate with NaOH the products obtained is/are:

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  13. Which statement is wrong about chloroform?

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  14. Which is the correct formula of freon 12?

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  15. Which of the following alkyl halides on hydrolysis gives a glycol?

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  16. The primary product of hydrolysis of CH(3)I is:

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  17. Butyronitrile may be prepared by heating

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  18. Which of the following reactions of C2H5Br does not represent an examp...

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  19. Amongst the following, which are true for S(N^2) reaction ? (i) The ra...

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  20. An organic compound undergoes addition reactions and gives a red preci...

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