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A compound (A) is formed by the reaction...

A compound (A) is formed by the reaction of ethylene with bromine which on reacting with aqueous KOH gives a compound (B). The compound (B) can also be prepared by the reaction of ethylene with the following:

A

Baeyer’s reagent

B

Oxygen in the presence of silver catalyst and then acidic hydrolysis

C

performic acid and the product undergoes acidic hydrolysis

D

All of the above

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The correct Answer is:
To solve the problem, we will break it down into steps: ### Step 1: Identify Compound A - **Reaction**: Ethylene (C2H4) reacts with bromine (Br2). - **Mechanism**: The double bond in ethylene attacks one of the bromine atoms, leading to the formation of a bromonium ion. The other bromine ion then attacks from the backside, resulting in a vicinal dibromide. - **Product A**: The product formed is 1,2-dibromoethane (BrCH2-CHBr). ### Step 2: Identify Compound B - **Reaction**: Compound A (1,2-dibromoethane) reacts with aqueous KOH. - **Mechanism**: The hydroxide ions (OH-) from KOH perform a bimolecular nucleophilic substitution (SN2) reaction, replacing the bromine atoms with hydroxyl groups. - **Product B**: The product formed is ethylene glycol (HO-CH2-CH2-OH), also known as ethane-1,2-diol. ### Step 3: Check Other Reagents for Formation of Compound B We need to determine whether the following reagents can also yield compound B (ethylene glycol) when reacted with ethylene. 1. **Baeyer’s Reagent (KMnO4)** - **Reaction**: Ethylene reacts with Baeyer’s reagent (acidified KMnO4). - **Mechanism**: KMnO4 oxidizes ethylene to form a diol. - **Product**: The product is again ethylene glycol (HO-CH2-CH2-OH). - **Conclusion**: This reagent can form compound B. 2. **Oxygen in the Presence of Silver Catalyst** - **Reaction**: Ethylene reacts with oxygen in the presence of a silver catalyst. - **Mechanism**: This reaction leads to the formation of an epoxide (cyclic ether). - **Hydrolysis**: The epoxide can then be hydrolyzed (using acidic conditions) to yield ethylene glycol. - **Product**: The product is ethylene glycol (HO-CH2-CH2-OH). - **Conclusion**: This reagent can also form compound B. 3. **Performic Acid** - **Reaction**: Ethylene reacts with performic acid (HCO3H). - **Mechanism**: Similar to the previous reactions, an epoxide is formed, which can be hydrolyzed. - **Hydrolysis**: The hydrolysis of the epoxide yields ethylene glycol. - **Product**: The product is ethylene glycol (HO-CH2-CH2-OH). - **Conclusion**: This reagent can also form compound B. ### Final Conclusion Since all the reagents (Baeyer’s reagent, oxygen with silver catalyst, and performic acid) lead to the formation of compound B (ethylene glycol), the correct answer is: - **All of the above**.
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