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100ml of 0.2 M H(2)SO(4) is added to 100...

`100ml` of `0.2 M H_(2)SO_(4)` is added to `100 ml` of `0.2 M NaOH`. The resulting solution will be

A

Acidic

B

Basic

C

Neutral

D

Slightly basic

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of mixing 100 mL of 0.2 M H₂SO₄ with 100 mL of 0.2 M NaOH, we will calculate the milli-equivalents of both the acid and the base and determine the nature of the resulting solution. ### Step-by-Step Solution: 1. **Calculate the milli-equivalents of H₂SO₄:** - Molarity (M) of H₂SO₄ = 0.2 M - Volume (V) of H₂SO₄ = 100 mL - n-factor of H₂SO₄ = 2 (because it dissociates into 2 H⁺ ions) - Formula for milli-equivalents (meq) = Molarity × Volume (in mL) × n-factor \[ \text{meq of H₂SO₄} = 0.2 \, \text{M} \times 100 \, \text{mL} \times 2 = 40 \, \text{meq} \] 2. **Calculate the milli-equivalents of NaOH:** - Molarity (M) of NaOH = 0.2 M - Volume (V) of NaOH = 100 mL - n-factor of NaOH = 1 (because it dissociates into 1 OH⁻ ion) - Using the same formula for milli-equivalents: \[ \text{meq of NaOH} = 0.2 \, \text{M} \times 100 \, \text{mL} \times 1 = 20 \, \text{meq} \] 3. **Compare the milli-equivalents:** - Milli-equivalents of H₂SO₄ = 40 meq - Milli-equivalents of NaOH = 20 meq Since the milli-equivalents of H₂SO₄ (40 meq) are greater than those of NaOH (20 meq), we conclude that H₂SO₄ is in excess. 4. **Determine the nature of the resulting solution:** - Since H₂SO₄ is in excess, the resulting solution will be acidic. ### Final Answer: The resulting solution will be acidic. ---
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