Home
Class 12
CHEMISTRY
Why the coordination number of CsCl chan...

Why the coordination number of CsCl changes from 8 : 8 to 6 : 6 coordination?

Text Solution

Verified by Experts

On heating to 760 K, CsCl changes to NaCl structure. In other words, high temperature decreases co-ordination number.
Promotional Banner

Topper's Solved these Questions

  • THE SOLID STATE

    VMC MODULES ENGLISH|Exercise EXERCISE - A|10 Videos
  • THE SOLID STATE

    VMC MODULES ENGLISH|Exercise EXERCISE- B|10 Videos
  • THE SOLID STATE

    VMC MODULES ENGLISH|Exercise ILLUSTRATIONS|24 Videos
  • SURFACE CHEMISTRY

    VMC MODULES ENGLISH|Exercise PRACTICE EXERCISE|9 Videos
  • THEORY OF SOLUTIONS

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|31 Videos

Similar Questions

Explore conceptually related problems

8:8 coordination of CsCl is found to change into 6:6 coordination :

What is the coordination unmber of Cs^(+) in CsCl ?

A : In NaCl coordination number of Cl^(-) ion is 6 but in CsCl coordination number of Cl^(-) ion is 8. R : Ionic radii changes with type of lattice.

What is the coordination number of Co in [Co(NH_3)_6]^(3+) ?

6 :6 of NaCl coordination changes to 8 : 8 coordination on:

Assertion (A) : CsCl crystal, the coordination number of Cs^(o+) ion is 8 . Reason (R ) : Cl^(ɵ) ion in CsCl adopt bcc type of packing,

Mark the correct statements regarding the geometry of complex ions . (i) The geometry of the complex ion depends upon the coordination number . (ii) If coordination number is 6 , the complex is octahedral . (iii) If coordination number is 4 , the geometry of the complex may be tetrahedral or square planar .

The coordination number of a central ion may be obtained from

The coordination number of a metal in coordination compound is

VMC MODULES ENGLISH-THE SOLID STATE-EXAMPLE
  1. Which one is not property of crystalline solid?

    Text Solution

    |

  2. A match box exhibits

    Text Solution

    |

  3. Which one is very soft in nature?

    Text Solution

    |

  4. A compound XY crystallizes in BCC lattice with unit cell-edge length o...

    Text Solution

    |

  5. If the edge-length of the unit cell of sodium chloride is 600 pm, and ...

    Text Solution

    |

  6. In a cubic close packed structure of mixed oxides, the lattice is made...

    Text Solution

    |

  7. In a metal M having bcc arrangement edge length of the unit cell is 40...

    Text Solution

    |

  8. The ratio of close packed atoms to tetrahedral holes in cubic close pa...

    Text Solution

    |

  9. In a face centered cubic arrangement of A and B atoms whose A atoms ar...

    Text Solution

    |

  10. For the structure given below the site marked as S is a

    Text Solution

    |

  11. An element with bcc structure has 12.08xx 1023 unit cells. The number ...

    Text Solution

    |

  12. The basic unit of all silicates is

    Text Solution

    |

  13. A binary solid A^(+)B^(-) has a structure with B^(-) ions constituting...

    Text Solution

    |

  14. Why the coordination number of CsCl changes from 8 : 8 to 6 : 6 coordi...

    Text Solution

    |

  15. How can you determine the atomic mass of an unknown metal if you know ...

    Text Solution

    |

  16. Copper crystallizer into an fcc lattice with edge length 3.61 xx 10^(-...

    Text Solution

    |

  17. Analysis shows that nickel oxide has the formula Ni(0.00). What fracti...

    Text Solution

    |

  18. A compound CuCl has face - centred cubic structure. Its density is 3.4...

    Text Solution

    |

  19. Aluminium crystallises in a cubic close-packed structuure. Its metalli...

    Text Solution

    |

  20. A compound formed by elements A and B crystallizes in cubic structure ...

    Text Solution

    |