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Which of the following statement(s) is i...

Which of the following statement(s) is incorrect?

A

The coordination number of each type of ion in CsCl crystal is 8

B

A metal that crystallizes in bcc structure has a coordination number of 12

C

A unit cell of an ionic crystal shares some of its ions with other unit cells

D

The length of the unit cell in NaCl is 552 pm `(r_(Na^+)=95"pm",r_(Cr^-)=181"pm")`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the following statements is incorrect, we will analyze each option one by one. ### Step-by-Step Solution: 1. **Analyze Option A**: - Statement: "The coordination number of each type of ion in CsCl crystal is 8." - **Explanation**: CsCl (cesium chloride) has a body-centered cubic (BCC) structure. In this structure, each Cs⁺ ion is surrounded by 8 Cl⁻ ions and vice versa. Therefore, the coordination number for both ions is indeed 8. - **Conclusion**: Option A is **correct**. 2. **Analyze Option B**: - Statement: "Metal has a crystal in BCC structure has coordination number 12." - **Explanation**: In a body-centered cubic (BCC) structure, the coordination number is 8, not 12. The coordination number of 12 is characteristic of face-centered cubic (FCC) structures. - **Conclusion**: Option B is **incorrect**. 3. **Analyze Option C**: - Statement: "The unit cell of an ionic crystal shares some of its ions with other unit cells." - **Explanation**: In ionic crystals, ions at the edges and corners of the unit cell are shared with adjacent unit cells. This is a characteristic feature of ionic crystals. - **Conclusion**: Option C is **correct**. 4. **Analyze Option D**: - Statement: "The length of a unit cell in NaCl is given by a specific formula." - **Explanation**: The unit cell length (A) in NaCl can be derived from the radii of the ions. The relationship is given by the equation \( r_{Na^+} + r_{Cl^-} = \frac{A}{2} \). This is consistent with the structure of NaCl. - **Conclusion**: Option D is **correct**. ### Final Conclusion: - The only incorrect statement among the options is **Option B**.
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