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Acetaldehyde reacts with C(2) H(3) MgCl ...

Acetaldehyde reacts with `C_(2) H_(3) MgCl` the final product is

A

An aldehyde

B

A ketone

C

A primary alcohol

D

A secondary alcohol

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of what product is formed when acetaldehyde reacts with C2H5MgCl (a Grignard reagent), we can follow these steps: ### Step 1: Identify the Reactants We have acetaldehyde (CH3CHO) and the Grignard reagent (C2H5MgCl). ### Step 2: Understand the Reaction Mechanism Grignard reagents react with carbonyl compounds (like aldehydes and ketones) to form alcohols. In this case, acetaldehyde is an aldehyde. ### Step 3: Nucleophilic Attack The Grignard reagent (C2H5-) acts as a nucleophile and attacks the electrophilic carbon of the carbonyl group in acetaldehyde. The reaction can be represented as follows: - The nucleophile (C2H5-) attacks the carbonyl carbon (C=O) of acetaldehyde. ### Step 4: Formation of the Intermediate This nucleophilic attack leads to the formation of a tetrahedral intermediate. The structure of the intermediate can be represented as: - CH3C(OH)(C2H5)MgCl. ### Step 5: Protonation When water (or a dilute acid) is added to the reaction mixture, the intermediate is protonated. The oxygen atom in the intermediate will attract a proton (H+) from water, leading to the formation of an alcohol. ### Step 6: Final Product The final product after the protonation step is: - CH3C(OH)(C2H5), which is a secondary alcohol because the carbon bearing the hydroxyl group (OH) is attached to two other carbon atoms. ### Conclusion Thus, the final product of the reaction between acetaldehyde and C2H5MgCl is a secondary alcohol. ### Final Answer The final product is a secondary alcohol. ---
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