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Aromatic aldehydes undero disproportiona...

Aromatic aldehydes undero disproportionation in presence of sodium or potassium hydroxide to give corresponding alcohol and acid. The reaction is known as `:`

A

Wurtz's reaction

B

Cannizzaro reaction

C

Friedel-Craft's reaction

D

Claisen reaction

Text Solution

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The correct Answer is:
To solve the question regarding the disproportionation of aromatic aldehydes in the presence of sodium or potassium hydroxide, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Disproportionation**: Disproportionation is a reaction where a single substance is transformed into two different products, typically involving the oxidation of one part and the reduction of another. 2. **Identifying the Reaction**: In this case, aromatic aldehydes undergo disproportionation in the presence of a strong base (sodium or potassium hydroxide). This means that the aldehyde will be converted into an alcohol and a carboxylic acid. 3. **Example Reaction**: For example, if we take benzaldehyde (C6H5CHO) as the aromatic aldehyde, the reaction can be represented as: \[ 2 \, C_6H_5CHO + NaOH \rightarrow C_6H_5COONa + C_6H_5CH_2OH \] Here, one molecule of benzaldehyde is oxidized to form benzoic acid (C6H5COOH), while another molecule is reduced to form benzyl alcohol (C6H5CH2OH). 4. **Naming the Reaction**: This specific reaction is known as the **Cannizzaro Reaction**. It is characteristic of non-enolizable aldehydes (like benzaldehyde) that do not have alpha-hydrogens. 5. **Conclusion**: Therefore, the correct answer to the question is that the reaction is known as the **Cannizzaro Reaction**. ### Final Answer: The reaction is known as the **Cannizzaro Reaction**. ---
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