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At 25°C the specific conductance of a 1N...

At `25°C` the specific conductance of a 1N solution of KCl is` 0.002765` mho. The resistance of cell is `400 Omega`. The cell constant is:

A

`0.815 cm^(–1)`

B

`1.016 cm^(–1)`

C

`1.106 cm^(–1)`

D

`2.016 cm^(–1)`

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The correct Answer is:
To find the cell constant of a conductivity cell, we can use the relationship between specific conductance (κ), resistance (R), and the cell constant (L/A). The cell constant is defined as the ratio of the length of the cell (L) to the cross-sectional area (A) of the electrodes. ### Step-by-step Solution: 1. **Identify the given values:** - Specific conductance (κ) = 0.002765 mho/cm (or ohm⁻¹ cm⁻¹) - Resistance (R) = 400 Ω 2. **Understand the relationship:** The cell constant (L/A) can be calculated using the formula: \[ \text{Cell Constant} (L/A) = \kappa \times R \] where κ is the specific conductance and R is the resistance. 3. **Substitute the values into the formula:** \[ L/A = 0.002765 \, \text{ohm}^{-1} \, \text{cm}^{-1} \times 400 \, \text{Ω} \] 4. **Calculate the cell constant:** \[ L/A = 0.002765 \times 400 \] \[ L/A = 1.106 \, \text{cm}^{-1} \] 5. **Final Answer:** The cell constant is \(1.106 \, \text{cm}^{-1}\).
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