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The degree of dissociation (alpha) of CH...

The degree of dissociation `(alpha)` of `CH_(3)COOH` solution having 0.1M concentration and pKa as 6, in presence of strong acid HCl having concentration 0.1M is `10^(-x)`. Then what is the value of x?

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To solve the problem, we need to find the degree of dissociation (α) of acetic acid (CH₃COOH) in the presence of a strong acid (HCl) and determine the value of x in the expression \(10^{-x}\). ### Step-by-Step Solution: 1. **Identify Given Values:** - Concentration of CH₃COOH = 0.1 M - pKa of acetic acid = 6 - Concentration of HCl = 0.1 M 2. **Calculate Ka from pKa:** \[ pKa = -\log(Ka) \implies Ka = 10^{-pKa} = 10^{-6} \] 3. **Set Up the Dissociation Reaction:** The dissociation of acetic acid can be represented as: \[ CH₃COOH \rightleftharpoons CH₃COO^- + H^+ \] Let the degree of dissociation be α. Therefore, the concentration of dissociated acetic acid will be: - Concentration of \(CH₃COO^-\) = \(0.1α\) - Concentration of \(H^+\) from acetic acid = \(0.1α\) 4. **Consider the Contribution of HCl:** Since HCl is a strong acid, it will completely dissociate: \[ HCl \rightarrow H^+ + Cl^- \] Thus, the concentration of \(H^+\) from HCl = 0.1 M. 5. **Total Concentration of H⁺ Ions:** The total concentration of \(H^+\) ions in the solution will be: \[ [H^+] = 0.1 + 0.1α \] 6. **Apply the Acid Dissociation Constant Expression:** The expression for the acid dissociation constant \(Ka\) is given by: \[ Ka = \frac{[CH₃COO^-][H^+]}{[CH₃COOH]} \] Substituting the known values: \[ 10^{-6} = \frac{(0.1α)(0.1 + 0.1α)}{0.1(1 - α)} \] 7. **Simplify the Equation:** Since α is very small (as indicated by the problem), we can approximate \(1 - α \approx 1\): \[ 10^{-6} = \frac{0.1α(0.1 + 0.1α)}{0.1} \] This simplifies to: \[ 10^{-6} = α(0.1 + 0.1α) \] 8. **Neglect the α² Term:** Since α is very small, we can neglect the \(0.1α^2\) term: \[ 10^{-6} = 0.1α \] 9. **Solve for α:** \[ α = \frac{10^{-6}}{0.1} = 10^{-5} \] 10. **Determine x:** The problem states that \(α = 10^{-x}\). Therefore: \[ 10^{-x} = 10^{-5} \implies x = 5 \] ### Final Answer: The value of \(x\) is **5**.

To solve the problem, we need to find the degree of dissociation (α) of acetic acid (CH₃COOH) in the presence of a strong acid (HCl) and determine the value of x in the expression \(10^{-x}\). ### Step-by-Step Solution: 1. **Identify Given Values:** - Concentration of CH₃COOH = 0.1 M - pKa of acetic acid = 6 - Concentration of HCl = 0.1 M ...
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