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The freezing point depression constant f...

The freezing point depression constant for water is `= 1.86^@C` m . If 5.00 g `Na SO_4` is dissolved in 45.0 g H,O, the freezing point is changed by `-3.82^@C`. Calculate the van't Hoff factor for `Na SO_4`

A

2.05

B

2.63

C

3.11

D

0.381

Text Solution

Verified by Experts

The correct Answer is:
B

We know that, `DeltaT_f =ixx k_f xx(w_Bxx1000)/(m_Bxxw_A)`
Given : `DeltaT_f = 3.82, K_f= 1.86`
`w_f = 5, m_B = 142, w_A= 45`
`(DeltaT_f xx m_Bxxw_A)/(K_f xxw_Bxx1000) = (3.82xx142 xx 45)/(1.86 xx 5 xx 1000) = 2.63`
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