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The mixture that forms maximum boiling a...

The mixture that forms maximum boiling azeotrope is

A

heptane + octane

B

water + nitric acid

C

ethanol + water

D

acetone + carbon disulphide.

Text Solution

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The correct Answer is:
B

Maximum boiling azeotropes are formed by those solutions which show negative deviations from Raoult.s law. `H_2O and HNO_3` mixture shows negative deviations.
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The solution which boil at constant temperature like a pure liquid and possess same composition in liquid as well as vapour state are called azeotropes. The components of azetropes cannot be separated by fractional distillation. Only non-ideal solutions form azeotropes. Solutions with negative deviation form maximum boiling azeotrope and the solutions with positive deviation form minimum boiling azeotrope. The boiling point of an azeotrope is never equal to the boiling points of any of the components of the azeotrope. Answer the following question: The azeotropic solutions of two miscible liquids Which among the following combinations is a maximum boiling azeotrope?

The solution which boil at constant temperature like a pure liquid and possess same composition in liquid as well as vapour state are called azeotropes. The components of azetropes cannot be separated by fractional distillation. Only non-ideal solutions form azeotropes. Solutions with negative deviation form maximum boiling azeotrope and the solutions with positive deviation form minimum boiling azeotrope. The boiling point of an azeotrope is never equal to the boiling points of any of the components of the azeotrope. Answer the following question: The azeotropic solutions of two miscible liquids 100 mL of liquid A and 50 mL of liquid B are mixed to form 138 mL solution. It is

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