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Using curved-arrow notation, show the fo...

Using curved-arrow notation, show the formation of reactive intermediates when the covalent bond undergo heterolytic cleavage.
`CH _(3) - SCH _(3),`

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Using curved-arrow notation, show the formation of reactive intermediates when the following covalent bonds undergo heterolytic cleavage. (a) CH_(3)-SCH_(3) , (b) CH_(3)-CN , (c ) CH_(3)-Cu

Explain the nature of the covalent bond using the bond formation in CH_3Cl .

For the following bond cleavages, use curved-arrows to show the electron flow and classify each as homolysis or heterolysis. Identify reactive intermediate produced as free radical, carbocation and carbanion. (a) CH_(3)O-OCH_(3)rarrCH_(3)overset(.)O+overset(.)(O)CH_(3) (b)

Explain the formation of CH_(3)I and phenol when anisole is heated with HI .

Bond energy : Energy required to break a bond (equal to the energy released when a bond is formed) is named bond energy. Its unit is Kcal/mole. Stability of bond energy 00 % s character oo(1)/(% "P character")oo "bond order" oo(1)/("bond length") Higher is the number of bonds at a place, higher is the bond energy. Which are true in terms of bond energy ? (i) CH_(3) -Fgt CH_(3) -Clgt CH_(3)- Brgt CH_(3)-1 (ii) H_(3) C - O lt H_(3) C - CH_(3) lt CH_(2) = CH -O - CH_(3) (iii) CH_(3) - CH_(2) -O - CH_(3) lt CH_(2) =CH-O -CH_(3) (iv) C- N gt N gt C = N (v) CH_(3) - CH_(2)- NH_(2) lt CH_(2) = CH -NH_(2) lt CH= C -NH_(2)

Bond energy : Energy required to break a bond (equal to the energy released when a bond is formed) is named bond energy. Its unit is Kcal/mole. Stability of bond energy 00 % s character oo(1)/(% "P character")oo "bond order" oo(1)/("bond length") Higher is the number of bonds at a place, higher is the bond energy. Write down rhe bond energy order of C_(2) - C_(3) in (A) CH_(3)- CH_(2)-CH_(2)-CH_(3) " " B ) CH_(3) -CH_(2)-CH= CH_(2) C) CH_(2)=CH-CH=CH_(2) " " D) CH_(2)=CH-C= CH E) CH_(3) - CH_(2) -C= CH " " F) CH = C- C= CH

Write the reactions showing the major and minor product when chlorobenzene is reacted with CH_(3) Cl and CH_(3) CO Cl in presence of AlCl_(3) .

VIKRAM PUBLICATION ( ANDHRA PUBLICATION)-ORGANIC CHEMISTRY SOME BASIC PRINCIPLES AND TECHNIQUES -IMPORTANT QUESTIONS
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