Equilibrium constant for the following reaction is `1xx10^(-9)` : `C_(5)H_(5)N(aq.)+H_(2)O(l)hArrC_(5)H_(5)NH^(+)(aq.)+OH^(-)(aq.)` Determine the moles of pyridinium chloride `(C_(5)H_(5)N.HCl)` that should be added t0 500 mL solution of 0.4 M pyridine `(C_(5)H_(5)N)` to obtain a buffer solution of pH=5 :