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Pick out the wrong reaction:...

Pick out the wrong reaction:

A

Boyle.s temperature `T_b = (Ra)/b`

B

Critical pressure `P_c = a/(27 b^2)`

C

Critical temperature `T_c = (8a)/(27 Rb)`

D

Critical volume `V_c = 3b`

Text Solution

Verified by Experts

The correct Answer is:
A

Boyle.s temperature: `T_b = a/(Rb)`
Boyle.s temperature `(T_b)` is the temperature at which is a real gas tend to behave ideally over a wide range of pressure.
`T_b = a/(R.b) = [(del(PV))/(del P)]_("limit" P to 0)`
At this temperature the effect of size of molecular and intermolecular forces roughly compensate each other.
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