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When Cr(s) + OH^(-)(aq) to Cr(OH)(4)^(-)...

When `Cr(s) + OH^(-)(aq) to Cr(OH)_(4)^(-) (aq) + H_(2)(g)` (basic solution) is balanced, the sum of the coefficients of all the reactants and products is:

A

14

B

15

C

17

D

9

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The correct Answer is:
To balance the reaction \( \text{Cr(s)} + \text{OH}^-(\text{aq}) \rightarrow \text{Cr(OH)}_4^-(\text{aq}) + \text{H}_2(g) \) in basic solution and find the sum of the coefficients of all the reactants and products, we can follow these steps: ### Step 1: Write the unbalanced equation The unbalanced equation is: \[ \text{Cr(s)} + \text{OH}^-(\text{aq}) \rightarrow \text{Cr(OH)}_4^-(\text{aq}) + \text{H}_2(g) \] ### Step 2: Identify the half-reactions We can break the overall reaction into two half-reactions: 1. Oxidation half-reaction: \( \text{Cr} \rightarrow \text{Cr(OH)}_4^- \) 2. Reduction half-reaction: \( \text{OH}^- \rightarrow \text{H}_2 \) ### Step 3: Balance the oxidation half-reaction For the oxidation half-reaction: \[ \text{Cr} \rightarrow \text{Cr(OH)}_4^- \] - Balance the oxygen by adding water: \[ \text{Cr} + 4\text{H}_2\text{O} \rightarrow \text{Cr(OH)}_4^- \] - Now, balance the hydrogen by adding \( \text{H}^+ \): \[ \text{Cr} + 4\text{H}_2\text{O} \rightarrow \text{Cr(OH)}_4^- + 8\text{H}^+ \] - Add \( \text{OH}^- \) to both sides to neutralize \( \text{H}^+ \): \[ \text{Cr} + 4\text{OH}^- \rightarrow \text{Cr(OH)}_4^- + 4\text{H}_2\text{O} \] - Balance the charge by adding electrons: \[ \text{Cr} + 4\text{OH}^- + 3\text{e}^- \rightarrow \text{Cr(OH)}_4^- + 4\text{H}_2\text{O} \] ### Step 4: Balance the reduction half-reaction For the reduction half-reaction: \[ \text{OH}^- \rightarrow \text{H}_2 \] - Balance the oxygen by adding water: \[ 2\text{OH}^- \rightarrow \text{H}_2 + \text{H}_2\text{O} \] - Balance the hydrogen by adding \( \text{OH}^- \): \[ 2\text{OH}^- \rightarrow \text{H}_2 + 2\text{H}^+ \] - Add \( \text{OH}^- \) to both sides to neutralize \( \text{H}^+ \): \[ 2\text{OH}^- + 2\text{H}_2\text{O} \rightarrow \text{H}_2 + 3\text{OH}^- \] - Balance the charge by adding electrons: \[ 2\text{OH}^- + 2\text{H}_2\text{O} + 2\text{e}^- \rightarrow \text{H}_2 + 3\text{OH}^- \] ### Step 5: Equalize the number of electrons To combine the half-reactions, we need to make sure the number of electrons is equal. We can multiply the oxidation half-reaction by 2 and the reduction half-reaction by 3: - Oxidation half-reaction (multiplied by 2): \[ 2\text{Cr} + 8\text{OH}^- + 6\text{e}^- \rightarrow 2\text{Cr(OH)}_4^- + 8\text{H}_2\text{O} \] - Reduction half-reaction (multiplied by 3): \[ 6\text{OH}^- + 6\text{H}_2\text{O} + 6\text{e}^- \rightarrow 3\text{H}_2 + 9\text{OH}^- \] ### Step 6: Combine the half-reactions Now, we can combine the two half-reactions: \[ 2\text{Cr} + 8\text{OH}^- + 6\text{e}^- + 6\text{OH}^- + 6\text{H}_2\text{O} + 6\text{e}^- \rightarrow 2\text{Cr(OH)}_4^- + 8\text{H}_2\text{O} + 3\text{H}_2 + 9\text{OH}^- \] ### Step 7: Simplify the equation After canceling out the electrons and simplifying, we arrive at the balanced equation: \[ 2\text{Cr} + 8\text{OH}^- \rightarrow 2\text{Cr(OH)}_4^- + 3\text{H}_2 \] ### Step 8: Calculate the sum of coefficients Now, we can find the sum of the coefficients: - For reactants: \( 2 + 8 = 10 \) - For products: \( 2 + 3 = 5 \) Thus, the total sum of coefficients is: \[ 10 + 5 = 15 \] ### Final Answer The sum of the coefficients of all the reactants and products is **15**.

To balance the reaction \( \text{Cr(s)} + \text{OH}^-(\text{aq}) \rightarrow \text{Cr(OH)}_4^-(\text{aq}) + \text{H}_2(g) \) in basic solution and find the sum of the coefficients of all the reactants and products, we can follow these steps: ### Step 1: Write the unbalanced equation The unbalanced equation is: \[ \text{Cr(s)} + \text{OH}^-(\text{aq}) \rightarrow \text{Cr(OH)}_4^-(\text{aq}) + \text{H}_2(g) \] ...
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