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Which of the following is true for the s...

Which of the following is true for the species having `3d^(4)` configuration?
(A) `Cr^(2+)` is reducing in nature.
(B) `Mn^(3+)` is oxidising in nature.
(C) Both (A) and (B)
(D) None of these

A

`Cr^(2+)` is reducing in nature.

B

`Mn^(3+)` is oxidising in nature

C

Both (a) and (b)

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
C

`Cr^(2+)` is reducing as its configuration, changes from `d^(5)` to `d.` , the latter having a half-filled `t_(2g)` level. On the other hand, the change from `Mn^(3+)` to `Mn^(2+)` results in the half-filled `(d^(5))` configuration which has extra stability.
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