Home
Class 11
CHEMISTRY
In the detection of group III cations (e...

In the detection of group III cations (eq. `Al^(3+)`) in the qualitative analysis of salts, `NH_(4)Cl` is added before adding `NH_(4)OH`. This is meant

A

to provide a definitely basic medium

B

to suppress the ionisation of the `NH_(4)OH`

C

to cause the precipitation of the chlorides of group III cations

D

to increase the solubility of the salt in water

Text Solution

Verified by Experts

The correct Answer is:
B
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL AND IONIC EQUILIBRIUM

    BRILLIANT PUBLICATION|Exercise LEVEL - II|60 Videos
  • CHEMICAL AND IONIC EQUILIBRIUM

    BRILLIANT PUBLICATION|Exercise LEVEL - II (Assertion-Reason)|5 Videos
  • CHEMICAL BONDING

    BRILLIANT PUBLICATION|Exercise LEVEL-III ( Linked Comprehension Type )|12 Videos

Similar Questions

Explore conceptually related problems

In the detection of group II cations in the qualitative analysis of salts. HCl is added before passing H_(2)S . This is meant

In a lab work, a teacher has given zinc salt solution for systematic analysis to two students studetn I added NH_4Cl followed by NH_4OH and student II added NH_4OH followed by NH_4Cl for the analyse of group III cations. In the systematic analysis of group III - cations, what is the role of NH_4Cl ?

Tollen's reagent is used for the detection of aldehyde when a solution of AgNO_(3) is added to glucose with NH_(4)OH then gluconic acid is formed Ag^(+) + e^(-) rarr Ag , E_("red")^(@)= 0.8V C_(6)H_(12)O_(6) + e^(-) rarr C_(6)H_(12) O_(7) (Gluconic acid) +2H^(+) + 2e^(-) , E_("red")^(@)= -0.05V Ag(NH_(3))_(2)^(+) + e^(-) rarr Ag(s) + 2NH_(3) , E^(@)= -0.337V [Use 2.303 xx (RT)/(F)= 0.0592 and (F)/(RT)= 38.92 at 298K] When ammonia is added to the solution, pH is raised to 11. Which half-cell reaction is affected by pH and by how much ?

Tollen's reagent is used for the detection of aldehyde when a solution of AgNO_(3) is added to glucose with NH_(4)OH then gluconic acid is formed Ag^(+) + e^(-) rarr Ag , E_("red")^(@)= 0.8V C_(6)H_(12)O_(6) + e^(-) rarr C_(6)H_(12) O_(7) (Gluconic acid) +2H^(+) + 2e^(-) , E_("red")^(@)= -0.05V Ag(NH_(3))_(2)^(+) + e^(-) rarr Ag(s) + 2NH_(3) , E^(@)= -0.337V [Use 2.303 xx (RT)/(F)= 0.0592 and (F)/(RT)= 38.92 at 298K] Ammonia is always added in this reaction. Which of the following must be incorrect ?

The IUPAC name of [Pt(NH_3)_4 (NO_2)Cl] SO_4 is

In a lab work, a teacher has given zinc salt solution for systematic analysis to two students studetn I added NH_4Cl followed by NH_4OH and student II added NH_4OH followed by NH_4Cl for the analyse of group III cations. Predict the observation of each student. Give reasons for difference in observation in any.

In a certain isomer of [Co(NH_(3))_(4)Cl_(2)] , the Cl-Co-Cl angle is 90^(@) . The isomer is known as

Write down the ionisation isomer of [Co(NH_3)_5Cl]SO_4