Home
Class 11
CHEMISTRY
Assertion : A process for which Delta ("...

Assertion : A process for which `Delta _("Ssystem") gt0` as well as `Delta H gt 0,` passes from non-spontaneous to spontaneous state as temperature is increased.
Reason : At higher temperature `T Delta S` exceeds `DeltaH.`

A

and (R) are correct and (R) is the correct explanation of(A).

B

If both (A) and (R) are correct, but (R) is not the correct explanation of(A).

C

If(A) is correct, but (R) is incorrect.

D

If both (A) and (R) are incorrect.

Text Solution

Verified by Experts

The correct Answer is:
A

`(because Delta G = Delta H - T Delta S.` For spontancity `Delta G =- ve)i.e., lt 0` so that `Delta H - T Delta S lt 0 or Delta H lt T Delta S or T Delta Sgt Delta H)`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL THERMODYNAMICS

    BRILLIANT PUBLICATION|Exercise LEVEL-III|52 Videos
  • CHEMICAL THERMODYNAMICS

    BRILLIANT PUBLICATION|Exercise LEVEL-II|102 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    BRILLIANT PUBLICATION|Exercise QUESTION (LEVEL -ll)|42 Videos
  • CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES

    BRILLIANT PUBLICATION|Exercise QUESTIONS (LEVEL-III ( Linked Comprehension Type ))|12 Videos

Similar Questions

Explore conceptually related problems

If 'Delta H_ sot gt0' for a solid, predict the effect of temperatüre on,its solubility?

Most of the naturally occurring processes are spontaneous. a) Give the criteria for spontaneity of a process in terms of free energy change ( DeltaG ) b) Exothermic reactions associated with a decrease in entropy are sponaneous at lower temperatures. Justify on the basis of Gibbs equation. c) Find the temperature above which the reactin MgO_((s))+C_((s))rightarrow Mg_((s))+CO_((g)) becomes spontaneous. (Given ( Delta_rH^theta=490kJmol^-1 & Delta_rS^theta=198JK mol^-1 )

Write the condition of temperature for a process to be spontaneous whose DeltaH and DeltaS values are positive. [Hint: DeltaG = DeltaH - TDeltaS]

BRILLIANT PUBLICATION-CHEMICAL THERMODYNAMICS -LEVEL-II (Assertion-Reason Type)
  1. Assertion : Heat of neutralisation of HNO3, and NaOH is almost same as...

    Text Solution

    |

  2. Assertion : Anexothermic process which is non spontaneous at high temp...

    Text Solution

    |

  3. Assertion : There is no change in internal energy in a cyclic process....

    Text Solution

    |

  4. Assertion : During an adiabatic process, heat energy is not exchanged ...

    Text Solution

    |

  5. Assertion : For an isothermal reversible process Q=-Wi.e. work done by...

    Text Solution

    |

  6. Assertion : The heat absorbed during the isothermal expansion of an id...

    Text Solution

    |

  7. Assertion : Decrease in free energy causes spontaneous reaction. Rea...

    Text Solution

    |

  8. Assertion : The enthalpy of both graphite and diamond is taken to be z...

    Text Solution

    |

  9. Assertion : When a gas at high pressure expands against vacuum, the wo...

    Text Solution

    |

  10. Assertion : A process for which Delta ("Ssystem") gt0 as well as Delta...

    Text Solution

    |

  11. Assertion : There is no reaction known for which Delta G is positive, ...

    Text Solution

    |

  12. Assertion : For every chemical reaction at equilibrium, standard Gibbs...

    Text Solution

    |

  13. Assertion : The enthalpy of formation of gaseous oxygen molecules at 2...

    Text Solution

    |

  14. Assertion : Molar entropy ofvaporisation of water is different from et...

    Text Solution

    |

  15. Assertion : If both Delta H ^(@) and Delta S ^(@) are positive then r...

    Text Solution

    |

  16. Assertion : There is exchange in internal energy in a cyclic process. ...

    Text Solution

    |

  17. Assertion : There is a natural asymmetry between converting work to he...

    Text Solution

    |

  18. Assertion : A reaction which is spontaneous and accompanied by decreas...

    Text Solution

    |