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Aluminium chloride exists as a dimer, Al...

Aluminium chloride exists as a dimer, `Al_2Cl_6` in solid state as well as in solution of non-polar solvents such as benzene. When dissolved in water, it gives:

A

`Al^(3+) + 3Cl^(ѳ)`

B

`Al_2O_3 +6HCl`

C

`[Al(H_2O)_6]^(3+) + 3Cl^(ѳ)`

D

`[Al(OH)_6]^(3-) + 3HCl`

Text Solution

Verified by Experts

The correct Answer is:
C

The dimeric form `Al_2Cl_6` is retained in non-polar solvent but is broken into `[Al(H_2O)_6]Cl_3` on dissolution in water due to high heat of hydration.
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