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Which of the following pairs represents ...

Which of the following pairs represents linkage isomers?

A

`[Cu(NH_3)_4][PtCl_4]` and `[Pt(NH_3)_4][CuCl_4]`

B

`[Pb(PPh_3)_2 (NCS)_2]` and `[Pd(PPh_3)_2(SCN)_2]`

C

`[Co(NH_3)_5 NO_3] SO_4` and `[Co(NH_3)_5 SO_4]NO_3`

D

`[PtCl_2(NH_3)_4]Br_2` and `[PtBr_2 (NH_3)_4]Cl_2`

Text Solution

Verified by Experts

The correct Answer is:
B
Linkage isomerism are caused due to presence of ambidentate ligands: `[Pd(PPh_3)_2(NCS)_2]` and`[Pd(PPh_3)_2(SCN)_2]` are linkage isomers due to-SCN, ambidentate ligands.
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