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Which ofthe following complexions is exp...

Which ofthe following complexions is expected to absorb visible light?

A

`[Ti(en)_2 (NH_3)_2]^(4+)`

B

`[Cr(NH_3)_6]^(3+)`

C

`[Zn(NH_3)_6]^(2+)`

D

`[Sc(H_2O)_3 (NH_3)_3]^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
B

`d^(0) (Ti^(4+) , Sc^(3+))` and `d^(10) (Zn^(2+))`species will not absorb visible light and are colourless, paramagnetic and hence whereas `d^3 (Cr^(3+))` can undergo d-d transition or absorption of visible light of a particular wavelength and will be coloured.
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