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The average distance between molecules o...

The average distance between molecules of an ideal gas at STP is approximately of the order of

A

1nm

B

100 nm

C

100 cm

D

`1 mu m`

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The correct Answer is:
To find the average distance between molecules of an ideal gas at standard temperature and pressure (STP), we can follow these steps: ### Step 1: Understand the Ideal Gas Law The ideal gas law is given by the equation: \[ PV = nRT \] Where: - \( P \) = Pressure (in Pascals) - \( V \) = Volume (in cubic meters) - \( n \) = Number of moles - \( R \) = Universal gas constant (\( 8.314 \, \text{J/(mol K)} \)) - \( T \) = Temperature (in Kelvin) ### Step 2: Set the Conditions for STP At standard temperature and pressure (STP): - Pressure, \( P = 1 \, \text{atm} = 10^5 \, \text{Pa} \) - Temperature, \( T = 273 \, \text{K} \) - Volume, \( V = 1 \, \text{m}^3 \) ### Step 3: Calculate the Number of Moles Using the ideal gas law, we can rearrange the equation to find the number of moles \( n \): \[ n = \frac{PV}{RT} \] Substituting the values: \[ n = \frac{(10^5 \, \text{Pa})(1 \, \text{m}^3)}{(8.314 \, \text{J/(mol K)})(273 \, \text{K})} \] Calculating the denominator: \[ 8.314 \times 273 \approx 2270.62 \] Now substituting back: \[ n \approx \frac{10^5}{2270.62} \approx 44 \, \text{moles} \] ### Step 4: Calculate the Number of Molecules To find the total number of molecules, we multiply the number of moles by Avogadro's number (\( N_A \)): \[ N = n \times N_A \] Where \( N_A \approx 6.02 \times 10^{23} \, \text{molecules/mol} \). Substituting the values: \[ N \approx 44 \times 6.02 \times 10^{23} \approx 2.65 \times 10^{25} \, \text{molecules} \] ### Step 5: Calculate the Average Distance Between Molecules The average distance \( d \) between molecules can be approximated using the formula: \[ d \approx \left( \frac{1}{N} \right)^{1/3} \] Substituting the value of \( N \): \[ d \approx \left( \frac{1}{2.65 \times 10^{25}} \right)^{1/3} \] Calculating: \[ d \approx (3.77 \times 10^{-26})^{1/3} \approx 1.56 \times 10^{-9} \, \text{m} \] ### Step 6: Convert to Nanometers Converting meters to nanometers: \[ d \approx 1.56 \, \text{nm} \] ### Final Answer The average distance between molecules of an ideal gas at STP is approximately of the order of \( 1 \, \text{nm} \). ---

To find the average distance between molecules of an ideal gas at standard temperature and pressure (STP), we can follow these steps: ### Step 1: Understand the Ideal Gas Law The ideal gas law is given by the equation: \[ PV = nRT \] Where: - \( P \) = Pressure (in Pascals) - \( V \) = Volume (in cubic meters) ...
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