Home
Class 12
CHEMISTRY
The most suitable reagent for the conver...

The most suitable reagent for the conversion of 2-phenylpropanamide into 1-phenylethylamine is :-

A

`H_2 Pd //C `

B

`Br_2 ,NaOH `

C

`LiAilH_4 , Et _2 O`

D

`NaBH_ 4 , Me OH `

Text Solution

AI Generated Solution

The correct Answer is:
To convert 2-phenylpropanamide into 1-phenylethylamine, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of 2-Phenylpropanamide**: - The molecular structure of 2-phenylpropanamide can be represented as: \[ \text{C}_6\text{H}_5-\text{C}(\text{C}_2\text{H}_5)-\text{C}(=O)-\text{NH}_2 \] - Here, the phenyl group (C6H5) is attached to the second carbon of the propanamide structure. 2. **Determine the Target Product**: - The target product is 1-phenylethylamine, which can be represented as: \[ \text{C}_6\text{H}_5-\text{C}(\text{C}_2\text{H}_5)-\text{NH}_2 \] - This structure has one less carbon than the starting material, indicating a potential loss of a carbon atom during the reaction. 3. **Identify the Suitable Reaction**: - To convert an amide to an amine while reducing the carbon count by one, we can use the Hofmann degradation reaction. This reaction specifically allows for the conversion of amides to amines with the loss of one carbon atom. 4. **Select the Reagent**: - The reagent used in the Hofmann degradation reaction is bromine (Br2) in the presence of a strong base, such as sodium hydroxide (NaOH). - Therefore, the reaction can be summarized as: \[ \text{2-Phenylpropanamide} + \text{Br}_2 + \text{NaOH} \rightarrow \text{1-Phenylethylamine} + \text{byproducts} \] 5. **Conclusion**: - The most suitable reagent for the conversion of 2-phenylpropanamide into 1-phenylethylamine is **Br2 in the presence of NaOH**. ### Final Answer: The correct answer is **Br2 in presence of NaOH**.

To convert 2-phenylpropanamide into 1-phenylethylamine, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of 2-Phenylpropanamide**: - The molecular structure of 2-phenylpropanamide can be represented as: \[ \text{C}_6\text{H}_5-\text{C}(\text{C}_2\text{H}_5)-\text{C}(=O)-\text{NH}_2 ...
Promotional Banner

Topper's Solved these Questions

  • QUESTION PAPER 2020

    KVPY PREVIOUS YEAR|Exercise PART-II(CHEMISTRY)|10 Videos
  • QUESTION PAPER 2020

    KVPY PREVIOUS YEAR|Exercise PART-II : CHEMISTRY |5 Videos
  • QUESTION PAPER 2013

    KVPY PREVIOUS YEAR|Exercise PART-II ( CHEMISTRY)|10 Videos
  • SOLVED PAPER 2018

    KVPY PREVIOUS YEAR|Exercise EXAMPLE|30 Videos
KVPY PREVIOUS YEAR-QUESTION PAPER 2020-PART-I (CHEMISTRY )
  1. The Stability of Follow the order

    Text Solution

    |

  2. Among the following, the biodegradable polymer is :

    Text Solution

    |

  3. Among the following, the compounds which can be reduced with for...

    Text Solution

    |

  4. An organic compound that is commonly used for sanitizing surfaces is :

    Text Solution

    |

  5. The rates of reaction of NaOH with follow the order :-

    Text Solution

    |

  6. The most suitable reagent for the conversion of 2-phenylpropanamide in...

    Text Solution

    |

  7. The compound X in the following reaction scheme :

    Text Solution

    |

  8. A nucleus X captures a beta particle and then emits a neutron and gamm...

    Text Solution

    |

  9. The boiling point (in ""^@C) of 0.1 molal aqueous solution of CuSO4.5H...

    Text Solution

    |

  10. A weak acid is titrated with a weak base. Consider the following statm...

    Text Solution

    |

  11. Products are favored in a chemical reaction taking place at a constan...

    Text Solution

    |

  12. A mixture of toluene and benzene forms a nearly ideal solution. Assume...

    Text Solution

    |

  13. Upon dipping a copper rod, the aqueous solution of the salt that can ...

    Text Solution

    |

  14. Treatment of alkaline KMnO4 solution with KI solution oxidizes iodide ...

    Text Solution

    |

  15. If an extra electron is added to the hypothetical molecule C2 this ext...

    Text Solution

    |

  16. Among the following the square planar geometry is exhibited by:

    Text Solution

    |

  17. The correct pair of orbitals involved in t-bonding between metal and C...

    Text Solution

    |

  18. The magnetic moment (in muB) of [Ni(dimethylglyxoimate)""2] complex is...

    Text Solution

    |

  19. A compound is formed by two elements M and N. Element N forms hexagona...

    Text Solution

    |

  20. If the velocity of the revolving electron of He^(+) in the first orbit...

    Text Solution

    |