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When a mixture of NaCl, K2Cr2O7 and conc...

When a mixture of NaCl, `K_2Cr_2O_7` and conc. `H_2SO_4` is heated in a dry test tube, a red vapour (X) is evolved. This vapour (X) turns an aqueous solution of NaOH yellow due to the formation of Y. X and Y. respectively. are:

A

`CrCl_3 and Na_2 Cr_2 O_7`

B

` Cr Cl_3 and Na_2 CrO_4`

C

`CrO_2 Cl_2 and Na_2CrO_4`

D

`Cr_2 (SO_4)_3 and Na_2 Cr_2 O_7`

Text Solution

Verified by Experts

The correct Answer is:
C

`4NaCl+ K_2 Cr_2 O_7 +6H_2 SO_4 to 4 Na HSO_4 + 2 KHSO_4 + 2 Cr O_2 Cl_2 (X ) +6 H_2 O`
` CrO_2 Cl_2 + 4Na OH to Na_2 CrO_4 (Y ) + 2NaCl +2H_2 O`
` X= CrO_2 Cl_2 `
` Y= Na_2 CrO_4`
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