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Ethyl cyanide (A) can be converted to et...

Ethyl cyanide (A) can be converted to ethyl amine (B) by :

A

`A overset(Sn//HCl) (to) B`

B

`A overset(H_(3) O^(+) ) (to)"" overset(NH_(3)// Delta)(to)"" overset(KBr O// Delta) (to) B`

C

`A overset(LiAlH_4) (to) B`

D

both (a), (c) are correct

Text Solution

AI Generated Solution

The correct Answer is:
To convert ethyl cyanide (A) to ethyl amine (B), we can follow these steps: ### Step 1: Identify the Structures - **Ethyl cyanide (A)** has the structure: CH3-CH2-C≡N (ethyl group attached to a cyano group). - **Ethyl amine (B)** has the structure: CH3-CH2-NH2 (ethyl group attached to an amine group). ### Step 2: Choose the Reaction Pathway To convert ethyl cyanide to ethyl amine, we can utilize a two-step reaction process: 1. **Hydrolysis of Ethyl Cyanide**: Treat ethyl cyanide with acidified water (H3O+). This will convert the cyano group (C≡N) into a carboxylic acid (C2H5COOH). 2. **Formation of Amide**: The carboxylic acid can then be reacted with ammonia (NH3) to form an amide (C2H5CONH2). 3. **Reduction of Amide to Amine**: Finally, treat the amide with KBr in the presence of a base to convert it into ethyl amine (C2H5NH2). ### Step 3: Write the Overall Reaction The overall reaction can be summarized as follows: 1. **Hydrolysis**: \[ CH3-CH2-C≡N + H3O^+ \rightarrow CH3-CH2-COOH \] 2. **Amidation**: \[ CH3-CH2-COOH + NH3 \rightarrow CH3-CH2-CONH2 \] 3. **Reduction**: \[ CH3-CH2-CONH2 + KBr \xrightarrow{\text{base, heat}} CH3-CH2-NH2 \] ### Conclusion The correct method to convert ethyl cyanide (A) to ethyl amine (B) is through the pathway involving hydrolysis to form a carboxylic acid, followed by amidation and reduction. Thus, the correct answer is option B. ---

To convert ethyl cyanide (A) to ethyl amine (B), we can follow these steps: ### Step 1: Identify the Structures - **Ethyl cyanide (A)** has the structure: CH3-CH2-C≡N (ethyl group attached to a cyano group). - **Ethyl amine (B)** has the structure: CH3-CH2-NH2 (ethyl group attached to an amine group). ### Step 2: Choose the Reaction Pathway To convert ethyl cyanide to ethyl amine, we can utilize a two-step reaction process: ...
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