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A mixed oxide of iron and chromium, FeO....

A mixed oxide of iron and chromium, `FeO.Cr_2O_3` is fused with sodium carbonate in the presence of air to form a yellow compound (A). On acidification, the compound (A) forms an orange coloured compound (B) which is a strong oxidising agent. Identify the compounds (A) and (B) .

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Since the inert pair effect is very prominent in Bi, therefore, its +5 oxidation state in much less stable than its +3 oxidation state. In other words, bismuth in the pentavalent state can easily accept two electrons and thus gets reduced to trivalent bismuth.
`Bi^(5+) + 2e^(-) to Bi^(3+)`
Therefore , it acts as a strong oxidising agent .
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BETTER CHOICE PUBLICATION-THE P-BLOCK ELEMENTS-QUESTION BANK
  1. Unlike "In"^+, Tl^+ is most stable with respect to disproportionation...

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  2. Explain inert pair effect with example.

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  3. A mixed oxide of iron and chromium, FeO.Cr2O3 is fused with sodium car...

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  4. Bismuth is a strong oxidising agent in the pentavalent state.

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  5. Explain why the first elements of a group differ from other elements o...

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  6. Why does Nitrogen show anomalous behaviour in its group ?

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  7. Nitrogen exists as diatomic molecule and phosphorous acts as tetra ato...

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  8. Why does the reactivity of nitrogen differ from phosphorus?

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  9. Give reasons for the low reactivity of nitrogen molecule.

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  10. Why does NH3 form hydrogen bond but PH3 does not?

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  11. PH3 has lower boiling point than NH3. Why?

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  12. Although fluorine is much more electronegative than hydrogen yet the d...

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  13. NCl3 is an endothermic compound while NF3 is an exothermic compound. e...

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  14. Explain some important characteristics of white and yellow phosphorus.

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  15. Why does nitrogen show catenation properties less than phosphorus ?

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  16. Unlike Phosphorus, nitrogen shows little tendency for catenation. Why?

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  17. Though nitrogen exhibits + 5 oxidation state, it does not form penta-h...

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  18. In the structure of HNO3 molecule, N-O bond (121 pm) is shorter that N...

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  19. SF6 molecule is kinetically an inert substance. Explain why?

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  20. SF6 is used in high voltage generators and switch gears. Why?

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