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Why does Nitrogen show anomalous behavio...

Why does Nitrogen show anomalous behaviour in its group ?

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Nitrogen, the first member of Group 15 elements, differ from other elements of the group due to the following reasions :
(i) It has very small size.
(ii) It has high electronegativity
(iii) It has high ionisation enthalpy.
(iv) It does not have d-orbitals in its valence shell.
(v) It forms multiple bonds easily.
Differences of nitrogen from other family members (Anomalous behaviour).
(i) Nitrogen is a gas while other elements are solids
(ii) Nitrogen can from hydrogen bonds while other elements of this group cannot do so.
(iii) Nitrogen does not form pentahalides while other elements form pentahalides.
(iv) Nitrogen exists as `N_2` while other family members cannot form stable diatomic molecules.
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BETTER CHOICE PUBLICATION-THE P-BLOCK ELEMENTS-QUESTION BANK
  1. Bismuth is a strong oxidising agent in the pentavalent state.

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  2. Explain why the first elements of a group differ from other elements o...

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  3. Why does Nitrogen show anomalous behaviour in its group ?

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  4. Nitrogen exists as diatomic molecule and phosphorous acts as tetra ato...

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  5. Why does the reactivity of nitrogen differ from phosphorus?

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  6. Give reasons for the low reactivity of nitrogen molecule.

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  7. Why does NH3 form hydrogen bond but PH3 does not?

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  8. PH3 has lower boiling point than NH3. Why?

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  9. Although fluorine is much more electronegative than hydrogen yet the d...

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  10. NCl3 is an endothermic compound while NF3 is an exothermic compound. e...

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  11. Explain some important characteristics of white and yellow phosphorus.

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  12. Why does nitrogen show catenation properties less than phosphorus ?

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  13. Unlike Phosphorus, nitrogen shows little tendency for catenation. Why?

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  14. Though nitrogen exhibits + 5 oxidation state, it does not form penta-h...

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  15. In the structure of HNO3 molecule, N-O bond (121 pm) is shorter that N...

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  16. SF6 molecule is kinetically an inert substance. Explain why?

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  17. SF6 is used in high voltage generators and switch gears. Why?

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  18. Why does ammonia act as a lewis base?

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  19. Explain why both N and Bi do not form pentahalides but Phosphorus does...

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  20. Give reason to explain +5 oxidation state is less stable than the +3 s...

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