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Why does the reactivity of nitrogen diff...

Why does the reactivity of nitrogen differ from phosphorus?

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Nitrogen exists as a diatomic molecule (N = N). Due to the presence of a triple bond between the two N-atoms, the bond dissociation energy is large. As a result, nitrogen is inert and unreactive in its elemental state.
In contrast, white or yellow phosphorus exists as a temperature molecule `(P_4)`. Since the P-P single bonds is much weaker than `N -= N` triple bond, therefore, phosphorus is much more reactive than nitrogen. Another factor for the large reactivity of phosphorus is the presence of angular strain in its molecule. Presence of angular strain in phosphorus makes it highly reactive.
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BETTER CHOICE PUBLICATION-THE P-BLOCK ELEMENTS-QUESTION BANK
  1. Why does Nitrogen show anomalous behaviour in its group ?

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  2. Nitrogen exists as diatomic molecule and phosphorous acts as tetra ato...

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  3. Why does the reactivity of nitrogen differ from phosphorus?

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  4. Give reasons for the low reactivity of nitrogen molecule.

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  5. Why does NH3 form hydrogen bond but PH3 does not?

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  6. PH3 has lower boiling point than NH3. Why?

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  7. Although fluorine is much more electronegative than hydrogen yet the d...

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  8. NCl3 is an endothermic compound while NF3 is an exothermic compound. e...

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  9. Explain some important characteristics of white and yellow phosphorus.

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  10. Why does nitrogen show catenation properties less than phosphorus ?

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  11. Unlike Phosphorus, nitrogen shows little tendency for catenation. Why?

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  12. Though nitrogen exhibits + 5 oxidation state, it does not form penta-h...

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  13. In the structure of HNO3 molecule, N-O bond (121 pm) is shorter that N...

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  14. SF6 molecule is kinetically an inert substance. Explain why?

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  15. SF6 is used in high voltage generators and switch gears. Why?

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  16. Why does ammonia act as a lewis base?

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  17. Explain why both N and Bi do not form pentahalides but Phosphorus does...

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  18. Give reason to explain +5 oxidation state is less stable than the +3 s...

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  19. Write balanced equation when ammonia is dissolved in water.

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  20. Describ chemistry of manufacture of ammonia by Haber's process and dis...

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