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Why does fluoriue show anomalous behavio...

Why does fluoriue show anomalous behaviour in its group ?

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The anomalous character of fluorine is due to
(a) its small size
(b) highest electronegativity
(c) low F-F bond dissociation energy and
(d) non-availability of d-orbitals in Valence shell.
Examples of anomalous character of fluorine.
(i) Most of the reactions of `F_2` are exothermic. It is due to small and strong bond formed by it with other elements.
(ii) It forms only one oxoacid, HOF while other halogens form a number of oxoacids.
(iii) HF is liquid at room temperature due to H-bonding, while other hydrogen halides are gases under similar conditions.
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BETTER CHOICE PUBLICATION-THE P-BLOCK ELEMENTS-QUESTION BANK
  1. Write the chemical equations when: Sugar reacts with conc. H2SO4.

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  2. SO3 has zero dipole moment. Why ?

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  3. Why does fluoriue show anomalous behaviour in its group ?

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  4. Why are halogens most reactive ?

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  5. Explain why Bond dissociation energy of F2 is less than that of Cl2 ?

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  6. Explain why F-F bond in fluorine is weaker than Cl-Cl bond in chlori...

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  7. Explain the following : HF is a weaker acid than HI.

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  8. Explain the following : Iodine is more soluble in KI solution than i...

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  9. Explain the following : Fluorine does not show positive oxidation st...

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  10. Explain the following : Iodine forms I3^- but F2^ does not form F3^-...

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  11. Explain: Electron gain enthalpy of chlorine is more negative than fluo...

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  12. Why electron affinity of fluorine is less than that of chlorine ?

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  13. Boiling point of HCI is lower than HF . Explain why?

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  14. Why are halogens coloured ?

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  15. Halogens have maximum negative electron gain enthalpy in the respectiv...

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  16. Electron gain enthalpy of chlorine is more negative as compared to flu...

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  17. Considering the parameters such as bond dissociation enthalpy, electro...

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  18. Why is fluorine a very reactive halogen ?

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  19. Account for the following: Among the halogens F2 is the strongest oxid...

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  20. Fluorine exhibits only - 1 oxidation state whereas other halogens exhi...

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