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What inspired N. Bartlett,for carrying o...

What inspired N. Bartlett,for carrying out the reaction between Xe and `PtF_6`?

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N. Bartlett (1962) noticed that PtF6 (platinum hexafluoride) is a powerful oxidising agent and combined with molecular oxygen `(O_2)` to form an ionic compound dioxygenylhexafluoroplatinate(V) or `O_2^+ [PtF_6]^-` . Formation of this compound indicates that `PtF_6` can oxidise `O_2` to `O_2^+` ion .
`PtF_6 + O_2 (g) to O_2^+ [PtF_6]^- (s)`
Now Xenon and dioxygen have certain similarities like:
(i) First ionisation energy of xenon and dioxygen `(O_2)` molecule are almost equal.
(ii) Molecular size of oxygen and Xenon are almost equal.
Taking into account the above two factors, Bartlett argued that since oxygen combines with platinum hexafluoride, so Xenon should also form similar compound with platinum hexafluoride. When he mixed deep red vapours of PtF6 with an excess of Xe at room temperature an orange yellow solid of formula `Xe^+ [PtF6]^-` was formed.
`Xe(g) + PtF_6 (g) to Xe^+ [PtF_6]^- (s)`
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BETTER CHOICE PUBLICATION-THE P-BLOCK ELEMENTS-QUESTION BANK
  1. Why noble gases have very high values of ionisation enthalpies?

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  2. Why is helium placed in p-block elements although its last electron en...

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  3. What inspired N. Bartlett,for carrying out the reaction between Xe and...

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  4. What inspired N. Bartlett,for carrying out the reaction between Xe and...

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  5. Among noble gases, only Xe is known to form chemical compounds. Why ?

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  6. Why do noble gases form compounds with fluorine and oxygen ?

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  7. How are Xenon fluorides XeF2, XeF4 and XeF6 prepared ?

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  8. Discuss the structure of the XeF4 on the basis of VSEPR theory.

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  9. Discuss the structure of XeF2 on the basis of VSEPR teory.

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  10. How are XeO3 and XeOF4 prepared?

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  11. Discuss the shapes of XeO3, XeOF4, XeOF2, and XeO2 F2

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  12. Discuss the hydrolysis of XeF3. Does the hydrolysis of XeF6 lead to a ...

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  13. Give equation for the following: XeF2 + H2 O to

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  14. Give equation for the following: XeF6 + H2 O

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  15. Give equation for the following: XeF2 + PF5 to

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  16. Give equation for the following: XeF6 + NaF to

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  17. Give the structure of XeOF2 and state of hybridization of Xe in it.

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  18. Why is helium used in diving apparatus?

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  19. List the uses of neon and argon gases.

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  20. Give uses of argon, helium, neon, xenon and krypton gases.

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