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Equal volume of 10% (v//v) of HCI is mix...

Equal volume of `10% (v//v)` of `HCI` is mixed with `10%(v//v) NaOH` solution. If density of pure `NaOH` is `1.5` times that of pure `HCl` then the resultant solution be ?

A

basic

B

neutral

C

acidic

D

can't be predicted.

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The correct Answer is:
To solve the problem, we need to determine the nature of the resultant solution when equal volumes of 10% (v/v) HCl and 10% (v/v) NaOH are mixed, given that the density of pure NaOH is 1.5 times that of pure HCl. ### Step-by-Step Solution: 1. **Understanding the Concentration**: - A 10% (v/v) solution means that there are 10 mL of solute (HCl or NaOH) in every 100 mL of solution. - Since we are mixing equal volumes, let's assume we take 100 mL of each solution. 2. **Calculating the Volume of Solutes**: - For HCl: In 100 mL of 10% (v/v) HCl, the volume of HCl is 10 mL. - For NaOH: In 100 mL of 10% (v/v) NaOH, the volume of NaOH is also 10 mL. 3. **Density Relationship**: - Let the density of pure HCl be \( d \) g/mL. Then, the density of pure NaOH is \( 1.5d \) g/mL. 4. **Calculating Mass of HCl and NaOH**: - Mass of HCl in 10 mL = \( 10 \, \text{mL} \times d \, \text{g/mL} = 10d \, \text{g} \). - Mass of NaOH in 10 mL = \( 10 \, \text{mL} \times 1.5d \, \text{g/mL} = 15d \, \text{g} \). 5. **Calculating Moles of HCl and NaOH**: - Molar mass of HCl = 1 + 35.5 = 36.5 g/mol. - Molar mass of NaOH = 23 + 16 + 1 = 40 g/mol. - Moles of HCl = \( \frac{10d}{36.5} \). - Moles of NaOH = \( \frac{15d}{40} \). 6. **Calculating Moles**: - Moles of HCl = \( \frac{10d}{36.5} \approx 0.274d \). - Moles of NaOH = \( \frac{15d}{40} = 0.375d \). 7. **Comparing Moles**: - Since \( 0.375d > 0.274d \), it shows that there are more moles of NaOH than HCl. 8. **Determining the Nature of the Resultant Solution**: - Since NaOH is a strong base and there are more moles of NaOH than HCl, the resultant solution will be basic. ### Conclusion: The resultant solution is basic.

To solve the problem, we need to determine the nature of the resultant solution when equal volumes of 10% (v/v) HCl and 10% (v/v) NaOH are mixed, given that the density of pure NaOH is 1.5 times that of pure HCl. ### Step-by-Step Solution: 1. **Understanding the Concentration**: - A 10% (v/v) solution means that there are 10 mL of solute (HCl or NaOH) in every 100 mL of solution. - Since we are mixing equal volumes, let's assume we take 100 mL of each solution. ...
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