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A hydrate of magnesium iodide has a form...

A hydrate of magnesium iodide has a formula `Mgl_(2).xH_(2)O.A 1.055 g` sample is heated to a constant weight of `0.695 g`. What is the value of `x` ?

A

`2`

B

`4`

C

`6`

D

`8`

Text Solution

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The correct Answer is:
To find the value of \( x \) in the hydrate formula \( \text{MgI}_2 \cdot x \text{H}_2\text{O} \), we can follow these steps: ### Step 1: Determine the mass of water lost The mass of the hydrate before heating is given as \( 1.055 \, \text{g} \) and the mass after heating (the residue) is \( 0.695 \, \text{g} \). To find the mass of water lost during heating, we subtract the mass of the residue from the mass of the hydrate: \[ \text{Mass of water lost} = \text{Mass of hydrate} - \text{Mass of residue} = 1.055 \, \text{g} - 0.695 \, \text{g} = 0.360 \, \text{g} \] ### Step 2: Calculate the molar mass of \( \text{MgI}_2 \) The molar mass of magnesium iodide \( \text{MgI}_2 \) can be calculated as follows: - Molar mass of Mg = \( 24.31 \, \text{g/mol} \) - Molar mass of I = \( 126.90 \, \text{g/mol} \) Thus, the molar mass of \( \text{MgI}_2 \) is: \[ \text{Molar mass of } \text{MgI}_2 = 24.31 + 2 \times 126.90 = 24.31 + 253.80 = 278.11 \, \text{g/mol} \] ### Step 3: Set up the equation for the molar mass of the hydrate The molar mass of the hydrate \( \text{MgI}_2 \cdot x \text{H}_2\text{O} \) is given by: \[ \text{Molar mass of hydrate} = \text{Molar mass of } \text{MgI}_2 + x \times \text{Molar mass of } \text{H}_2\text{O} \] The molar mass of water \( \text{H}_2\text{O} \) is \( 18.02 \, \text{g/mol} \). Therefore, we can express the molar mass of the hydrate as: \[ \text{Molar mass of hydrate} = 278.11 + 18.02x \] ### Step 4: Use the mass ratio to find \( x \) According to the problem, the ratio of the mass of the hydrate to the mass of the residue (which is \( \text{MgI}_2 \)) should equal the ratio of their molar masses: \[ \frac{1.055 \, \text{g}}{0.695 \, \text{g}} = \frac{278.11 + 18.02x}{278.11} \] ### Step 5: Solve for \( x \) Cross-multiplying gives: \[ 1.055 \times 278.11 = 0.695 \times (278.11 + 18.02x) \] Calculating the left side: \[ 1.055 \times 278.11 \approx 293.57 \] Now calculating the right side: \[ 0.695 \times 278.11 + 0.695 \times 18.02x \] Calculating \( 0.695 \times 278.11 \): \[ 0.695 \times 278.11 \approx 193.20 \] So we have: \[ 293.57 = 193.20 + 0.695 \times 18.02x \] Subtract \( 193.20 \) from both sides: \[ 293.57 - 193.20 = 0.695 \times 18.02x \] \[ 100.37 = 0.695 \times 18.02x \] Now, calculate \( 0.695 \times 18.02 \): \[ 0.695 \times 18.02 \approx 12.52 \] So we have: \[ 100.37 = 12.52x \] Now, divide both sides by \( 12.52 \): \[ x = \frac{100.37}{12.52} \approx 8.01 \] Since \( x \) must be a whole number, we round it to \( x = 8 \). ### Final Answer Thus, the value of \( x \) is \( 8 \). ---

To find the value of \( x \) in the hydrate formula \( \text{MgI}_2 \cdot x \text{H}_2\text{O} \), we can follow these steps: ### Step 1: Determine the mass of water lost The mass of the hydrate before heating is given as \( 1.055 \, \text{g} \) and the mass after heating (the residue) is \( 0.695 \, \text{g} \). To find the mass of water lost during heating, we subtract the mass of the residue from the mass of the hydrate: \[ ...
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