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Given the equivalent conductance of sodi...

Given the equivalent conductance of sodium butyrate sodium chloride and hydrogen chloride as 83,127 and 426 mho `cm^(2)` at `25^(@)C` respectively the equivalent conductance of butyric acid at infinite dilution.

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To find the equivalent conductance of butyric acid at infinite dilution, we can use the given equivalent conductances of sodium butyrate, sodium chloride, and hydrogen chloride. Here's a step-by-step solution: ### Step 1: Write the equations for the given compounds 1. **Sodium Butyrate (C4H7COONa)**: \[ \Lambda^0_{\text{C4H7COONa}} = \Lambda^0_{\text{C4H7COO}^-} + \Lambda^0_{\text{Na}^+} \] Given: \(\Lambda^0_{\text{C4H7COONa}} = 83 \, \text{mho cm}^2\) 2. **Hydrochloric Acid (HCl)**: \[ \Lambda^0_{\text{HCl}} = \Lambda^0_{\text{H}^+} + \Lambda^0_{\text{Cl}^-} \] Given: \(\Lambda^0_{\text{HCl}} = 426 \, \text{mho cm}^2\) 3. **Sodium Chloride (NaCl)**: \[ \Lambda^0_{\text{NaCl}} = \Lambda^0_{\text{Na}^+} + \Lambda^0_{\text{Cl}^-} \] Given: \(\Lambda^0_{\text{NaCl}} = 127 \, \text{mho cm}^2\) ### Step 2: Set up the equations From the above equations, we can express the equivalent conductance of butyric acid (C4H7COOH) as: \[ \Lambda^0_{\text{C4H7COOH}} = \Lambda^0_{\text{C4H7COO}^-} + \Lambda^0_{\text{H}^+} \] ### Step 3: Eliminate the common ions To find \(\Lambda^0_{\text{C4H7COO}^-} + \Lambda^0_{\text{H}^+}\), we can use the following relationship: \[ \Lambda^0_{\text{C4H7COO}^-} + \Lambda^0_{\text{H}^+} = \Lambda^0_{\text{C4H7COONa}} + \Lambda^0_{\text{HCl}} - \Lambda^0_{\text{NaCl}} \] ### Step 4: Substitute the known values Now, substituting the known values into the equation: \[ \Lambda^0_{\text{C4H7COOH}} = 83 + 426 - 127 \] ### Step 5: Calculate the equivalent conductance Calculating the above expression: \[ \Lambda^0_{\text{C4H7COOH}} = 83 + 426 - 127 = 382 \, \text{mho cm}^2 \] ### Final Answer The equivalent conductance of butyric acid at infinite dilution is: \[ \Lambda^0_{\text{C4H7COOH}} = 382 \, \text{mho cm}^2 \] ---

To find the equivalent conductance of butyric acid at infinite dilution, we can use the given equivalent conductances of sodium butyrate, sodium chloride, and hydrogen chloride. Here's a step-by-step solution: ### Step 1: Write the equations for the given compounds 1. **Sodium Butyrate (C4H7COONa)**: \[ \Lambda^0_{\text{C4H7COONa}} = \Lambda^0_{\text{C4H7COO}^-} + \Lambda^0_{\text{Na}^+} \] Given: \(\Lambda^0_{\text{C4H7COONa}} = 83 \, \text{mho cm}^2\) ...
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ALLEN-ELECTROCHEMISTRY-EXERCISE-04 [A]
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